24. The cationic chain-growth, addition polymerization of a large excess of isobutylene (below) occurs in the presence of a catalytic amount of the initiator (2-chloro-2-phenyl- propane/boron trichloride). Draw the arrow pushing mechanisms for the initiation, propagation, and termination steps. Draw the structure of the polymer with correct end groups that would result from this polymerization.

Organic Chemistry
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ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter29: Organic Polymer Chemistry
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Problem 29.12P
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24. The cationic chain-growth, addition polymerization of a large excess of isobutylene
(below) occurs in the presence of a catalytic amount of the initiator (2-chloro-2-phenyl-
propane/boron trichloride). Draw the arrow pushing mechanisms for the initiation,
propagation, and termination steps. Draw the structure of the polymer with correct end
groups that would result from this polymerization.
CI
CH3
"CH3
CH3
BCI3
CH3
Transcribed Image Text:24. The cationic chain-growth, addition polymerization of a large excess of isobutylene (below) occurs in the presence of a catalytic amount of the initiator (2-chloro-2-phenyl- propane/boron trichloride). Draw the arrow pushing mechanisms for the initiation, propagation, and termination steps. Draw the structure of the polymer with correct end groups that would result from this polymerization. CI CH3 "CH3 CH3 BCI3 CH3
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