2NO2(g)+F2(g)→NO2F(g)ΔH∘rxn=−284kJ/molrxn NO2(g) and F2(g) can react to produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below. Step 1: NO2+F2→NO2F+F (slow) Step 2: NO2+F→NO2F (fast) (a) Write a rate law for the overall reaction that is consistent with the proposed mechanism.
2NO2(g)+F2(g)→NO2F(g)ΔH∘rxn=−284kJ/molrxn NO2(g) and F2(g) can react to produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below. Step 1: NO2+F2→NO2F+F (slow) Step 2: NO2+F→NO2F (fast) (a) Write a rate law for the overall reaction that is consistent with the proposed mechanism.
Chapter8: Reaction Rates And Equilibrium
Section: Chapter Questions
Problem 8.28E
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2NO2(g)+F2(g)→NO2F(g)ΔH∘rxn=−284kJ/molrxn
NO2(g) and F2(g) can react to produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below.
Step 1: | NO2+F2→NO2F+F | (slow) |
Step 2: | NO2+F→NO2F | (fast) |
(a) Write a rate law for the overall reaction that is consistent with the proposed mechanism.
Expert Solution
Step 1
The rate law of a reaction is determined experimentally by measuring the rate of reaction. In rate law, the sum of the power of the concentration term is known as the order of the reaction.
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