Consider the overall reaction: Cl_2 (aq)+H_2S (aq)--> S (s) +2HCl (aq). A proposed mechanism is Cl_2-->Cl^++Cl^- (slow) Cl^-+H_2S-->HCl+HS^- (fast) Cl^++HS^- -->HCl+S (fast) If this is the correct mechanism, which is the predicted rate expansion? i.) rate = k[Cl^+][Cl^-] ii.) rate = k[Cl_2][H_2S] iii.) rate = k[S][HCl]^2 iv.) rate = k[Cl_2]
Consider the overall reaction: Cl_2 (aq)+H_2S (aq)--> S (s) +2HCl (aq). A proposed mechanism is Cl_2-->Cl^++Cl^- (slow) Cl^-+H_2S-->HCl+HS^- (fast) Cl^++HS^- -->HCl+S (fast) If this is the correct mechanism, which is the predicted rate expansion? i.) rate = k[Cl^+][Cl^-] ii.) rate = k[Cl_2][H_2S] iii.) rate = k[S][HCl]^2 iv.) rate = k[Cl_2]
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 45PS
Related questions
Question
Consider the overall reaction: Cl_2 (aq)+H_2S (aq)--> S (s) +2HCl (aq). A proposed mechanism is
Cl_2-->Cl^++Cl^- (slow)
Cl^-+H_2S-->HCl+HS^- (fast)
Cl^++HS^- -->HCl+S (fast)
If this is the correct mechanism, which is the predicted rate expansion?
i.) rate = k[Cl^+][Cl^-]
ii.) rate = k[Cl_2][H_2S]
iii.) rate = k[S][HCl]^2
iv.) rate = k[Cl_2]
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning