step elementary reaction rate constant H2(g) + 2 NO(g) → N,0(g) + H,0(g) k1 2 H,(9) + N,0(g) N2(9) + H,O(g) k2 Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 2H, (g) + 2N0(g) → N,(g) + 2H,0(g) N, (g) + 2H,0(g) Write the experimentally- observable rate law for the overall chemical reaction. [H.][No]° rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k-2 for k, k2 k = k. the reverse of the two elementary reactions in the mechanism.

Chemistry: The Molecular Science
5th Edition
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Chapter12: Chemical Equilibrium
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step
elementary reaction
rate constant
H2(g) + 2 NO(g) → N,0(g) + H,0(g)
k1
2
H,(9) + N,0(g) N2(9) + H,O(g)
k2
Suppose also k,»k,. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
2H, (g) + 2N0(g) → N,(g) + 2H,0(g)
N, (g) + 2H,0(g)
Write the experimentally-
observable rate law for the
overall chemical reaction.
[H.][No]°
rate
= k
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k1, k2,
and (if necessary) the rate
constants k.1 and k-2 for
k, k2
k =
k.
the reverse of the two
elementary reactions in
the mechanism.
Transcribed Image Text:step elementary reaction rate constant H2(g) + 2 NO(g) → N,0(g) + H,0(g) k1 2 H,(9) + N,0(g) N2(9) + H,O(g) k2 Suppose also k,»k,. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 2H, (g) + 2N0(g) → N,(g) + 2H,0(g) N, (g) + 2H,0(g) Write the experimentally- observable rate law for the overall chemical reaction. [H.][No]° rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k.1 and k-2 for k, k2 k = k. the reverse of the two elementary reactions in the mechanism.
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