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- One famous application of nanomaterials are in the cosmetic industry, identify the nanometrials used in sunscreens. Explain the role of these materials in sunscreens.A compound of gallium with chlorine has a melting point of 350 K (77 °C) and a boiling point of 474 K (201 °C). Is the compound ionic or covalent? What is a likely formula?The interhalogen compound BrF3 is a volatile, straw-colored liquid. The compound exhibits appreciable electrical conductivitybecause of autoionization (“solv” refers to BrF3 as the solvent):2 BrF3(l) ⇌ BrF2+(solv) + BrF4- (solv)(a) What are the molecular structures of the BrF2+ and BrF4- ions?(b) The electrical conductivity of BrF3 decreases with increasing temperature. Is the autoionization process exothermic or endothermic?(c) One chemical characteristic of BrF3 is that it acts as a Lewis acid toward fluoride ions. What do we expect will happen whenKBr is dissolved in BrF3?
- The attractive force between two ions in Na20, Fc is 8.64x10-9N. What is the bond length a0 (in nm) given that valence of the charged Na+ is Z1=+1, for O-, is Z2 =-2, the charge of a single electron q is 0.16x10-18 C and the proportionality constant k0=9x109 V.m/C? Note that K=k0(Z1q)(Z2q) and that 1 V.C = 1 J.Q3: (A) Answer the following questions: 1. Give an example of allotropy materials and explain it. 2.State three types of smart materials. 3. What is bonding of NaCl ? List its properties and sketch this bond. 4. Explain Pauli principle.Mixing SbCl3 and GaCl3 in a 1;1 molar ratio (usingliquid sulfur dioxide as a solvent) gives a solid ioniccompound of empirical formula GaSbCl6. A controversyarises over whether this compound is ( ) SbCl2 + ( ) GaCl 4 - or( ) GaCl+ 2 ( ) SbCl 4 -(a) Predict the molecular structures of the two anions.(b) It is learned that the cation in the compound has abent structure. Based on this fact, which formulationis more likely to be correct?
- 8.13 In which of the following states would NaCl be electrically conducting: (a) solid, (b) molten (i.e., melted), (c) dissolved in water? Explain.State whether the bonding in each compound is likely to be covalent: i) glucose, ii) nitrogen, iii) aluminum hydroxide, iv) ammonia, v) neon. b) A substance, XY, formed from two different elements, melts at 350°C. Is XY likely to be a covalent or an ionic substance?How do the physical properties of a network covalent solidand a molecular covalent solid differ? Why?