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- A 370.00 mL solution of 0.00185 M A3B4 is added to a 390.00 mL solution of 0.00100 M C3D4. What is pQsp for A3D4?A 10.00cm3 portion of the 100.00cm3 HCl solut was taken from the volumetric flask and was titrated with KOH (aq). It was neeutralized by 24.35cm3 of potassium hydroxide od concentration 0.0500moldm-3. Calculate the concentrat of the original concentrated hydrochloric acid in moldm-3.) A truck driver carrying a load of lead nitrate (Pb(NO3)2) lost control of his semi- truck after hitting a patch of ice and crashed the truck into Blue Lake, which was right next to the highway. Despite the best efforts of the emergency workers, several of the crates containing lead nitrate were damaged, and the highly soluble compound dissolved immediately. Assuming the lake is initially at circumneutral pH (7), and that the spill resulted the in a total lead concentration of 10-3 M within the lake. Based on the following information, will PbO(s) precipitate out of Blue Lake. Assume all lead nitrate dissociates into Pb+2 and NO3-, no other sources of lead exist in the lake and that no other reactions besides the equations shown below occur. PbO(s) + 2H+ ⇌ PbO(s) + H+ ⇌ PbO(s) + H2O ⇌ PbO(s) + 2H2O ⇌ Pb2+ + H2O PbOH+ + H2O Pb(OH)2o Pb(OH)3- + H+ logKs0/ksp =14 logK1=3.4 logK2=-0.5 logK3=-12
- 1ml of 1mg/ml of diluted aspirin powder solution is titrated by 0.005M NaOH. Before titration, 5 ml ethanol, 14 ml CO2 free water, and 4 drops bromothymol blue indicator is added into diluted aspirin powder solution. Mass of 0.005M NaOH used is obtained by weight titration = 1.1384g . [Molar mass of aspirin =180.15]; for solution, 1g=1mL at 25 degree Celcius. Calculate the purity of the powder.v. What is pH? Calculate the pH for 0.0001N NH4OH solution of 100mL volume. The pKb value for NH4OH at 25oC is 1.76 x 10-5.What mass of Ba(OH)2 is present in a sample if it is titrated to its equivalence point with 44.20 mL of 0.1000 N H2SO4? Note: Present complete solutions for the following problem. Express your final answers up to two (2) decimal places.
- Ammonium acetate buffer is used as an important reagent for studying molecular biology, biological buffers, reagents and DNA and RNA purification. Ammonium acetate (0.24M) in combination with cold 66% (v/v) ethanol quantitatively precipitated RNA from very dilute solutions (greater than or equal to μg/ml) after centrifugation. Ammonium acetate (CH3COONH4) is also a salt of weak acid (CH3COOH) and weak base (NH4OH). The Ka and Kb are equal to 1.8 x10-5. The pH of this salt solution will be, a. pH > 7 b. pH ≈ 7 c. pH < 7 d. both cation and anion don’t hydrolyze. e. none of the above.You have performed an iodimetric titration using a commercial vitamin C tablet. Based on the following information below, calculate the %(w/w) of vitamin C(MM=176.16 g/mol) in the tablet: Mass of tablet dissolved in 250.0 mL: 5.422 g Aliquot volume of sample titrated: 25.00 mL Concentration of KIO3: 0.023 M Final burrette volume: 41.31 mL Initial burrette volume: 8.89 mL Blank volume: 0.14 mLA solution containing Mg2+ was buffered to pH 9.81 and titrated with EDTA. Eriochrome black T, with p?a1 = 6.3 and p?a2 = 11.6 was used as the indicator. It is a diprotic acid, H2E What is the fraction of the predominant form of eriochrome black T in solution at this pH? (To answer this, report the alpha fraction of the indicator’s most prevalent species at this pH)
- A sufficient quantity of each of the following aqueous solutions has been made available to you: (i) 0.2M NaH2PO4; (ii) 0.1M Na2HPO4 (a) How many ml of each of these two solutions would you require to mix together in order to prepare one litre of a 0.01M phosphate buffer pH 7.2? [For H3PO4: pKa1 = 2.15; pKa2 = 6.82; pKa3 = 12.38]. (Ans. = 14.7 ml 0.2M NaH2PO4; and 70.6 ml Na2HPO4). (b) Having calculated these volumes (of 0.2 M NaH2PO4 and 0.1M Na2HPO4) required, what further steps would you take to prepare the 0.01M phosphate buffer solution of pH 7.2?The acid- dissociated constant at 25.0 degres celcius for hypochlorous acid (HCIO) is 3.0x10-8. At equilibrium, the molarity of H3O+ in a 0.066M solution of HCIO is?A 250 cm3 volumetric flask contains exactly 200,0 cm3 of a 0,025 mol.dm3sulphuric acid solution. Thereafter ten (10) sodium hydroxide pellets, eachof mass 0,1 g are dropped into the flask. After the pellets have dissolvedcompletely, the flask is topped to the 250 cm3 mark with water and thecontents are thoroughly homogenised. Determine the pH of the resultingsolution.