A 0.4071-g sample of CaCO3 (MM: 100.09 g/mole) is transferred to a 500-mL volumetric flask, dissolved using a minimum of 6 M HCl, and diluted to volume. A 50.00-mL aliqout of this solution was mixed with 5 mL of a pH 10 NH3-NH4Cl buffer that contains a small amount of Mg2+--EDTA to adjust the pH to 10. After adding calmagite as an indicator, the solution is titrated with the EDTA, requiring 42.63 mL to reach the end point. Report the molar concentration of EDTA in the titrant.     9.543 x 10-3 M     5.748 x 10-3 M     3.266 x 10-4 M     1.018 x 10-4 M

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.20QAP
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  1. A 0.4071-g sample of CaCO3 (MM: 100.09 g/mole) is transferred to a 500-mL volumetric flask, dissolved using a minimum of 6 M HCl, and diluted to volume. A 50.00-mL aliqout of this solution was mixed with 5 mL of a pH 10 NH3-NH4Cl buffer that contains a small amount of Mg2+--EDTA to adjust the pH to 10. After adding calmagite as an indicator, the solution is titrated with the EDTA, requiring 42.63 mL to reach the end point. Report the molar concentration of EDTA in the titrant.

       

    9.543 x 10-3 M

       

    5.748 x 10-3 M

       

    3.266 x 10-4 M

       

    1.018 x 10-4 M

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