3.) Rationalize the formation of the indicated fragments in the IE mass spectrum of each of the following molecules by proposing a structure for the fragment and a curved arrow mechanism for its formation. (a.) A fragment with m/z = 73 from 3-methylhexan-3-ol (b.) A fragment with m/z = 70 from pentan-1-ol

3.) Rationalize the formation of the indicated fragments in the IE mass spectrum of each of the following molecules by proposing a structure for the fragment and a curved arrow mechanism for its formation. (a.) A fragment with m/z = 73 from 3-methylhexan-3-ol (b.) A fragment with m/z = 70 from pentan-1-ol

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....

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