32. Captopril is used to treat high blood pressure and congestive heart failure. Label the chiral center from left to right: HS CH3 a. R, R b. S, S c. R, S d. S, R 33. What are the assignments (Z/E) for the two alkenes below? Br F3C CląC a. E, E b. Z, Z c. E, Z d. Z, E

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter5: Stereochemistry At Tetrahedral Centers
Section5.SE: Something Extra
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32. Captopril is used to treat high blood pressure and congestive heart failure. Label the chiral
center from left to right:
HS
CH3
a. R, R
b. S, S
c. R, S
d. S, R
33. What are the assignments (Z/E) for the two alkenes below?
Br
F3C
Cl3C
a. E, E
b. Z, Z
c. E, Z
d. Z, E
34. What is the starting material for the reaction below?
1. BH
2. H,0,/OH
Me,CHCH,CHO
a. 3-methyl-2-butene
b. 3-methyl-1-butyne
c. 2-pentyne
d. 1-pentyne
35. Identify a pair of enantiomers:
Br
-CI
CI-
-B
Br
-CI
CI-
C-Br
Br-
-CI
CI-
Cl-
H.
H.
B
D
a. A and B
b. A and D
c. B and C
d. none
36. What mechanism(s) would you propose for the reaction below?
CH;OH
Br
a. SN2 & E2
b. Syl & El
c. SN2 & El
d. SN1 & E2
6.
Transcribed Image Text:32. Captopril is used to treat high blood pressure and congestive heart failure. Label the chiral center from left to right: HS CH3 a. R, R b. S, S c. R, S d. S, R 33. What are the assignments (Z/E) for the two alkenes below? Br F3C Cl3C a. E, E b. Z, Z c. E, Z d. Z, E 34. What is the starting material for the reaction below? 1. BH 2. H,0,/OH Me,CHCH,CHO a. 3-methyl-2-butene b. 3-methyl-1-butyne c. 2-pentyne d. 1-pentyne 35. Identify a pair of enantiomers: Br -CI CI- -B Br -CI CI- C-Br Br- -CI CI- Cl- H. H. B D a. A and B b. A and D c. B and C d. none 36. What mechanism(s) would you propose for the reaction below? CH;OH Br a. SN2 & E2 b. Syl & El c. SN2 & El d. SN1 & E2 6.
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