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3c) Determine the valence electron count of the complex shown below. Use both counting models and compare your results. Assume that the Re-N-O bonding angle is 180°. ON!...Re ORPPh3 Ph 3d) The nitrosyl cation is notorious for its ability to function as a non-innocent ligand. This means that coordinated NO* can affect the oxidation state of the metal to which it is bound. If the central atom M (1) can adopt more than one stable oxidation state and (2) if the metal is not too electronegative, the NO* can withdraw two electrons from M. Does this redox process alter the geometry of the originally linear M-N-O bond and the electron count of the nitrosyl ligand? If yes, describe the changes and the modifications that have to be made when determining the valence electron count.

3c) Determine the valence electron count of the complex shown below. Use both counting models and compare your results. Assume that the Re-N-O bonding angle is 180°. ON!...Re ORPPh3 Ph 3d) The nitrosyl cation is notorious for its ability to function as a non-innocent ligand. This means that coordinated NO* can affect the oxidation state of the metal to which it is bound. If the central atom M (1) can adopt more than one stable oxidation state and (2) if the metal is not too electronegative, the NO* can withdraw two electrons from M. Does this redox process alter the geometry of the originally linear M-N-O bond and the electron count of the nitrosyl ligand? If yes, describe the changes and the modifications that have to be made when determining the valence electron count.

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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3c) Determine the valence electron count of the complex shown below. Use both counting models and compare your results. Assume that the Re-N-O bonding angle is 180°. ON!...Re ORPPh3 Ph 3d) The nitrosyl cation is notorious for its ability to function as a non-innocent ligand. This means that coordinated NO* can affect the oxidation state of the metal to which it is bound. If the central atom M (1) can adopt more than one stable oxidation state and (2) if the metal is not too electronegative, the NO* can withdraw two electrons from M. Does this redox process alter the geometry of the originally linear M-N-O bond and the electron count of the nitrosyl ligand? If yes, describe the changes and the modifications that have to be made when determining the valence electron count.
Transcribed Image Text:3c) Determine the valence electron count of the complex shown below. Use both counting models and compare your results. Assume that the Re-N-O bonding angle is 180°. ON!...Re ORPPh3 Ph 3d) The nitrosyl cation is notorious for its ability to function as a non-innocent ligand. This means that coordinated NO* can affect the oxidation state of the metal to which it is bound. If the central atom M (1) can adopt more than one stable oxidation state and (2) if the metal is not too electronegative, the NO* can withdraw two electrons from M. Does this redox process alter the geometry of the originally linear M-N-O bond and the electron count of the nitrosyl ligand? If yes, describe the changes and the modifications that have to be made when determining the valence electron count.
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