4. A student has prepared 0.05 M solution of CH3-C=CH and has added to it 0.05 M solution of potassium tert-butoxide (K* O-C(CH3)3). (iv) Calculate the percentage of deprotonated methyl acetylene taking into account that pKa of the conjugate acid of potassium tert-butoxide equals 18 and pKa of methyl acetylene equals 24.
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- I’m currently trying to write a lab report for the synthesis of dimolybdenum tetraacetate [Mo2(O2CCH3)4] from the reaction of molybdenum hexacarbonyl, Mo(CO)6 in glacial acetic acid and acetic anhydride under a nitrogen atmosphere, involving the difficult formation of a quadruple bond and requires high heat and long reaction time (approximately 20 hours). But these are the question I’m stumped on: 1. Why need the reaction be done under nitrogen? We also added dichlorobenzene and hexanes during the reaction. 2. Explain the purpose of dichlorobenzene and hexanes. 3. Why does the reaction take 20 hrs?Explain why the hydrolysis of [Co(NH3)5Cl]2+ in the presence of base muchfaster than that of [Co(py)5Cl]2+? Illustrate your answer with suitable diagrams.Discuss comprehensively why -Cl and -NO2 aredeactivators and why -Cl is a weak and -NO2 astrong deactivator?
- One of the heptanedione isomers below has a pka of approximately 9 rather than 20. Which isomer? Why? Draw its conjugate base and offer a full explanation of its acidity.For each of the following mixtures of reactants, give (i) a plausible chemical equation and (ii) structurefor the organometallic product, and (iii) general reason for the course of the reaction: (a)methyllithium and W(CO)6, (b) Co2(CO)8 and AlBr3.at 25C, which of the following reactions of PbS and H2O2 is more favourable?1) PbS + 4H2O2 -> SO2 + PbO2 + 4H2O2) PbS + H2O2 -> PbSO4 + H2O
- please provide the machanisms of 1a, 1e, 1fA) Provide the reagent and reaction mechanism to show how the reactants and products in the following reaction can interconvert B) under what conditions would the reaction I) favour reactants, II) favour the products and III) why?Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4AI(C2H5)3 →3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d = 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3): d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257 L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?
- 3 Give mechanisms for the acid-catalyzed and base-promoted alpha-halogenation ofketones. Explain why multiple halogenations are common with basic catalysis andgive a mechanism for the haloform reactionGive detailed answer- Provide example of compound that fulfil each criteria below. Explain why-A)1,2-disconnectionB)1,4-disconnectionC)1,5-disconnectionD)1,6-disconnectionChemistry Give the products of the reaction of 1 mole of 2-methy1-1,3-pentadiene with 1 mole of HBr. Whichproduct(s) will predominate if the reaction is under kinetic control? Which products) will predominateif the reaction is under thermodynamic control?