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- What is the likely mechanism of nucleophilic substitution for each alkyl halide?Draw the major organic product of this E1 elimination reaction. Ignore byproducts.The following reaction takes place several times faster than the reaction of 2-chlorobutane with HO-: a. Explain the enhanced reaction rate.b. Explain why the OH group in the product is not bonded to the carbon that was bonded to the Cl group in the reactant.
- a. Draw the structures of all the elimination products. b. The reaction occurs through an E2 mechanism. Using one of your products writethe mechanism of the reaction using curved arrows. c. Is this reaction regioselective? Explain your answer. d. Explain why the reaction is stereoselective.Rank the following dienophiles in order of increasing reactivity.Iodoethane does not react via Sn2 reaction with NaI in Acetone. It is a good leaving group and on the primary carbon, why doesn't it react Sn2? (I know it reacts Sn1)
- a,b-Unsaturated carbonyl compounds are susceptible to either 1,2 addition or 1,4 (Michael)addition. Give examples of nucleophiles that would favor each case and explain yourreasoningWhich halide in the attached marine natural product reacts fastest inthe SN2 reaction?What is the best way to remeber the differences between Sn1, Sn2, E1 and E2 reations?
- Attached compounds undergoes E2 elimination with strongbase? For compounds that undergo elimination, draw the product. Forcompounds that do not undergo elimination, explain why they are unreactive.What two sets of reagents (each consisting of a carbonyl compound and phosphonium ylide) can be used for the synthesis of the following alkene? a. What alkyl halide is required to prepare each of the phosphonium ylides? b. What is the best set of reagents to use for the synthesis?Which benzylic halide reacts faster in an SN1 reaction? Explain.