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- Draw the aldol product for the reaction of the aldehyde shown with NaOH. Assume the reaction is run under conditions that allow the reaction to stop before dehydration. u H NaOHThe following molecule can be formed via an intramolecular aldol addition reaction. Draw the organic starting material needed to form the given B-hydroxycarbonyl compound. organic starting material B-hydroxycarbonyl NaOH OH5. Propose a mechanism for the base-catalyzed hydrolysis of the nitrile. H₂O NaOH CEN 6. Propose a mechanism for aldol reaction. HiM Н н NaOH H₂O
- What is the general name for the reaction product formed in an aldol addition reaction? O y-Hydroxy carbonyl compound a,B-Hydroxy carbonyl compound O a-Hydroxy carbonyl compound O B-Hydroxy carbonyl compoundPropose an appropriate intermediate for the following reactionAldol Condensation Product ܘܡ Ph Aldol Addition Product
- What is the product formed when each dicarbonyl compound undergoes an intramolecular aldol reaction, followed by dehydration.2 H3C H3C H C→XT OH H3C The aldol reaction is a carbonyl condensation reaction between two carbonyl partners and involves a combination of nucleophilic addition and a-substitution steps. One partner is converted into an enolate ion nucleophile and adds to the electrophilic carbonyl group of the second partner. In the classic aldol reaction, the carbonyl partners are aldehydes or ketones, although aldehydes are more reactive. The product is a ß-hydroxy carbonyl compound. base :0: OH H H Under reaction conditions slightly more vigorous than those employed for the aldol reaction, the ß-hydroxyl group is eliminated in an E1cB dehydration to give an a,ß-unsaturated carbonyl compound. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instruct ns H3C heat OH H3C :0: H + H₂O H5. Consider the below aldol reaction. Draw the product if all reactants are consumed and condensation, if possible, occurs. +2 H H NaOH EtOH A
- Predict the products of aldol condensation, followed by dehydration, of the followingketones and aldehydes. c) cyclohexanoneWhat are the products of an aldol cyclization for the following compound?Why is the Aldol reaction often called an Aldol condensation? 1) The initially formed b-hydroxy carbonyl compound loses an oxygen atom 2) The initially formed b-hydroxy carbonyl compound loses a hydrogen atom 3) The initially formed b-hydroxy carbonyl compound loses water 4) The initially formed b-hydroxy carbonyl compound loses a hydroxyl group