4. What aldehyde or ketone is needed to synthesize each alcohol by metal hydride reduction? Draw the reaction mechanism OH X=

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterNW4: Nomenclature Worksheet 4: Carbonyl Compounds
Section: Chapter Questions
Problem 15CTQ
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CH,CCH
CH₂CH₂OH
(2)
a.
Name the 2 compounds above
b. Which is more acidic? Explain your answer
4. What aldehyde or ketone is needed to synthesize each alcohol by metal hydride reduction? Draw the
reaction mechanism
OH
X-
5. Starting from alkyl halide, indicate the reaction pathway that will produce the acid below:
CH,CH,COH
(1)
Transcribed Image Text:CH,CCH CH₂CH₂OH (2) a. Name the 2 compounds above b. Which is more acidic? Explain your answer 4. What aldehyde or ketone is needed to synthesize each alcohol by metal hydride reduction? Draw the reaction mechanism OH X- 5. Starting from alkyl halide, indicate the reaction pathway that will produce the acid below: CH,CH,COH (1)
1. a Rank the labeled protons in order of decreasing acidity.
b. Rank each group of compounds in order of decreasing acidity.
CO₂H
CO₂H
c. Discuss the effects of alkyl and electronegative substituent on pka of carboxylic acids
d. Name each the following carboxylic acids. Which is more acidic and why?
-OH
"T
2. Using curly arrows draw a stepwise mechanism for the following reaction. Name the reactant,
reagent and product
LIAIH
l
H₂O
OH
6
Transcribed Image Text:1. a Rank the labeled protons in order of decreasing acidity. b. Rank each group of compounds in order of decreasing acidity. CO₂H CO₂H c. Discuss the effects of alkyl and electronegative substituent on pka of carboxylic acids d. Name each the following carboxylic acids. Which is more acidic and why? -OH "T 2. Using curly arrows draw a stepwise mechanism for the following reaction. Name the reactant, reagent and product LIAIH l H₂O OH 6
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