Write the name of the coordination compound (1st row). If any, show all the possible structural, geometric and optical isomers for the coordination compounds (2nd row). Calculate the efective atomic number (EAN) of metal ion in the coordination compound and indicate whether or not coordination compound is stable according to the 18 Electron Rule (2nd row). Find the hybridization type and draw geometric structure of the coordination compound according to the Valence Bond Theory (VBT). Indicate that the coordination compound is inner or outher orbital complex, and paramagnetic or diamagnetic. if it is paramagnetic, indicate the number of unpaired electrons and calculate magnetic moment (Bohr magneton) (3th row), Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row). Draw the molecular orbital energy diagram of the coordination compound according to the Molecular Orbital Theory (MOT) (3th row). Explain whether the coordination compound shows John Teller Distortion. If any, elongation or compression? (3th row)

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9th Edition
ISBN:9781133611097
Author:Steven S. Zumdahl
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Chapter21: Transition Metals And Coordination Chemistry
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Problem 12Q
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Write the name of the coordination compound (1st row).
If any, show all the possible structural, geometric and optical isomers for the coordination compounds (2nd
row).
Calculate the efective atomic number (EAN) of metal ion in the coordination compound and indicate whether
or not coordination compound is stable according to the 18 Electron Rule (2nd row).
Find the hybridization type and draw geometric structure of the coordination compound according to the
Valence Bond Theory (VBT). Indicate that the coordination compound is inner or outher orbital complex, and
paramagnetic or diamagnetic. if it is paramagnetic, indicate the number of unpaired electrons and calculate
magnetic moment (Bohr magneton) (3th row),
Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the
coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row).
Draw the molecular orbital energy diagram of the coordination compound according to the Molecular Orbital
Theory (MOT) (3th row).
Explain whether the coordination compound shows John Teller Distortion. If any, elongation or compression?
(3th row)
Transcribed Image Text:Write the name of the coordination compound (1st row). If any, show all the possible structural, geometric and optical isomers for the coordination compounds (2nd row). Calculate the efective atomic number (EAN) of metal ion in the coordination compound and indicate whether or not coordination compound is stable according to the 18 Electron Rule (2nd row). Find the hybridization type and draw geometric structure of the coordination compound according to the Valence Bond Theory (VBT). Indicate that the coordination compound is inner or outher orbital complex, and paramagnetic or diamagnetic. if it is paramagnetic, indicate the number of unpaired electrons and calculate magnetic moment (Bohr magneton) (3th row), Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row). Draw the molecular orbital energy diagram of the coordination compound according to the Molecular Orbital Theory (MOT) (3th row). Explain whether the coordination compound shows John Teller Distortion. If any, elongation or compression? (3th row)
1st row
Nomenculation
[Pt(NH3)4(OH)2]SO4
[Pt(NH3)4][PtBr4]
[Pt(NH3)4][CuCl4]
[Co(NH3)4Brz]CI
[Cr(NH3)6][Co(CN)6]
K3[Fe(Ox)3]
Na3[Co(NO₂)6]
2nd row
Isomerism, EAN
Cl
[Co(NO₂)(SCN) (en)2]
[Co(NH3)4Cl2]NO₂
[Co(en)2(NH3)CI]SO4
[Cr(H₂O)4(NO2) CI] Br
[Co(en)2(NO₂)SCN] Br
[Pt(NH3)3Cl3] Br
[Co(NH3)sBr]SO4
M
3th row
VBT, CFT, MOT,
Jahn Teller
[FeF6]³
[Mn(CN)6]
[Cu(en)]2+
[Pd(NH3)6]4+
[Cr(H₂O)]3+
[Fe(CN)6]4
[Co[HzO)6]3+
Transcribed Image Text:1st row Nomenculation [Pt(NH3)4(OH)2]SO4 [Pt(NH3)4][PtBr4] [Pt(NH3)4][CuCl4] [Co(NH3)4Brz]CI [Cr(NH3)6][Co(CN)6] K3[Fe(Ox)3] Na3[Co(NO₂)6] 2nd row Isomerism, EAN Cl [Co(NO₂)(SCN) (en)2] [Co(NH3)4Cl2]NO₂ [Co(en)2(NH3)CI]SO4 [Cr(H₂O)4(NO2) CI] Br [Co(en)2(NO₂)SCN] Br [Pt(NH3)3Cl3] Br [Co(NH3)sBr]SO4 M 3th row VBT, CFT, MOT, Jahn Teller [FeF6]³ [Mn(CN)6] [Cu(en)]2+ [Pd(NH3)6]4+ [Cr(H₂O)]3+ [Fe(CN)6]4 [Co[HzO)6]3+
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