Answered: 5. In the lowest energy conformation of…

5. In the lowest energy conformation of the compound below, how many alkyl substituents are axial and how many are equatorial? m

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter7: Cycloalkanes

Section: Chapter Questions

Problem 9CTQ: a model of cyclohexane in a chair conformation, and explain why the names “axial” and“equatorial’...

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

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5.
In the lowest energy conformation of the compound below, how many alkyl substituents are
axial and how many are equatorial?
mmos maior
Label gach

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a model of cyclohexane in a chair conformation, and explain why the names “axial” and“equatorial’ are appropriate.
Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.
Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.
The diaxial conformation of cis-1, 3-dimethylcyclohexane is approximately 23 kJ/mol (5.4 kcal/mol) less stable than the diequatorial conformation. Draw the two possible chair conformations, and suggest a reason for the large energy difference.
Draw the Newman projections of the three p0ssible staggered c0nf0rmati0ns 0f 2,3-dimethylbutane, viewed through the C2—C3 b0nd. What are the relative energies 0f each conformation?
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Draw the two chair conformations of each compound, and label the substituents as axial and equatorial of cis-1-ethyl-4-methylcyclohexane
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Then draw the most stable and least stable Newman projection conformation from the C4-C5 bond in the molecule above
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