10.4.-#5. thank u 5. The decomposition of gaseous ozone 2 03 → 3 O2, exhibits a rate law given by- d[O:] / dt = k [O;J² / [O2]Show that this rate law follows from the mechanismki(1)O3O + 02k2k3>2 02(2)O3 + 0On the supposition that kɔ >> k3. What is the resulting expression for k?

This is a very interesting problem from kinetics. Please find the attached sheet for solution.

5. The decomposition of gaseous ozone 2 03 → 3 O2, exhibits a rate law given by - d[03] / dt = k [0;] / [O] Show that this rate law follows from the mechanism ki (1) 03 3 F 0 + 02 k2 (2) O3 + 0 k3 > 2 O2 On the supposition that k2 >> k3. What is the resulting expression for k?

5. The decomposition of gaseous ozone 2 03 → 3 O2, exhibits a rate law given by - d[03] / dt = k [0;] / [O] Show that this rate law follows from the mechanism ki (1) 03 3 F 0 + 02 k2 (2) O3 + 0 k3 > 2 O2 On the supposition that k2 >> k3. What is the resulting expression for k?

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 6ALQ: For the reaction A + B C, explain at least two ways in which the rate law could be zero order in...

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10.4.-#5. thank u

5. The decomposition of gaseous ozone 2 03 → 3 O2, exhibits a rate law given by
- d[O:] / dt = k [O;J² / [O2]
Show that this rate law follows from the mechanism
ki
(1)
O3
O + 02
k2
k3
>2 02
(2)
O3 + 0
On the supposition that kɔ >> k3. What is the resulting expression for k?

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