The decomposition of gaseous ozone 2 03 → 3 02, exhibits a rate law given by- d[O]] / dt = k [0;J / [0]Show that this rate law follows from the mechanismk1O3 Fk2(1)0 + O2(2)03 + 0k3>2 02On the supposition that k2 >> k3. What is the resulting expression for k?

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The decomposition of gaseous ozone 2 O3 → 3 O2, exhibits a rate law given by d[O}] / dt = k [O3] / [O2] Show that this rate law follows from the mechanism ki (1) O3 0 + 02 k2 k3 O3 + 0 (2) 2 O2 On the supposition that k2 >> k3. What is the resulting expression for k?

The decomposition of gaseous ozone 2 O3 → 3 O2, exhibits a rate law given by d[O}] / dt = k [O3] / [O2] Show that this rate law follows from the mechanism ki (1) O3 0 + 02 k2 k3 O3 + 0 (2) 2 O2 On the supposition that k2 >> k3. What is the resulting expression for k?

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.49PAE: The rate of photodecomposition of the herbicide piclo- ram in aqueous systems was determined by...

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Question

The decomposition of gaseous ozone 2 03 → 3 02, exhibits a rate law given by
- d[O]] / dt = k [0;J / [0]
Show that this rate law follows from the mechanism
k1
O3 F
k2
(1)
0 + O2
(2)
03 + 0
k3
>2 02
On the supposition that k2 >> k3. What is the resulting expression for k?

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