Using the following data below for the generic reaction A + B --> 2C + D , which obeys the rate equation d[D]/dt=k[A]α[B]β [A] (M) [B] (M) d[D]/dt (M/s) 0.300 0.300 1.31×10−5 0.600 0.300 3.69×10−5 0.300 0.600 1.85×10−5 a. What are the orders with respect to A and B (α,β)? What is the overall reaction order? b. What is the value of the rate constant k? Be sure to include units.
Using the following data below for the generic reaction A + B --> 2C + D , which obeys the rate equation d[D]/dt=k[A]α[B]β [A] (M) [B] (M) d[D]/dt (M/s) 0.300 0.300 1.31×10−5 0.600 0.300 3.69×10−5 0.300 0.600 1.85×10−5 a. What are the orders with respect to A and B (α,β)? What is the overall reaction order? b. What is the value of the rate constant k? Be sure to include units.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 6PS: 6. Phenyl acetate, an ester, reacts with water according to the equation
The data in the table were...
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Using the following data below for the generic reaction A + B --> 2C + D , which obeys the rate equation d[D]/dt=k[A]α[B]β
| [A] (M) | [B] (M) | d[D]/dt (M/s) |
| 0.300 | 0.300 | 1.31×10−5 |
| 0.600 | 0.300 | 3.69×10−5 |
| 0.300 | 0.600 | 1.85×10−5 |
a. What are the orders with respect to A and B (α,β)? What is the overall reaction order?
b. What is the value of the rate constant k? Be sure to include units.
c. Collecting concentration vs. time data would be another possible method to determine k. Describe and sketch the way you would plot these data to obtain a linear relationship, and how you would determine k based on this plot.
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