6. From the following enthalpies of reaction find AHan for 2 HCl(g) + F₂(g) ---> 2 HF(1) + Cl₂2(g) AHrxn= ? 4 HCl(g) + O₂(g) ---> 2 H₂O() +2 Cl₂(g) 1/2 H₂(g) + 1/2 F₂(g) ---> HF(1) H₂(g) + 1/2 O₂(g) ---> H₂O(l) a) +766 kJ/mol b) -988.4 kJ/mol AH = -148.4 kJ/mol AH-600.0 kJ/mol AH = -285.8 kJ/mol Ⓒ-840 kJ/mol d) +1337 kJ/mol

6. From the following enthalpies of reaction find AHan for 2 HCl(g) + F₂(g) ---> 2 HF(1) + Cl₂2(g) AHrxn= ? 4 HCl(g) + O₂(g) ---> 2 H₂O() +2 Cl₂(g) 1/2 H₂(g) + 1/2 F₂(g) ---> HF(1) H₂(g) + 1/2 O₂(g) ---> H₂O(l) a) +766 kJ/mol b) -988.4 kJ/mol AH = -148.4 kJ/mol AH-600.0 kJ/mol AH = -285.8 kJ/mol Ⓒ-840 kJ/mol d) +1337 kJ/mol

Chemistry

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 76E: Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and...

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Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and hydrogen are combusted, carbon dioxide and water are the products. Using the enthalpies of combustion for C4H4 ( 2341 kJ/mol), C4H8 (2755 kJ/mol), and H2 (286 kJ/mol), calculate H for the reaction C4H4(g)+2H2(g)C4H8(g)
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
9.102 A runner generates 418 kJ of energy per kilometer from the cellular oxidation of food. The runner's body must dissipate this heat or the body will overheat. Suppose that sweat evaporation is the only important cooling mechanism. If you estimate the enthalpy of evaporation of water as 44 kJ/mol and assume that sweat can he treated as water, describe how you would estimate the volume of sweat that would have to be evaporated if the runner runs a 10-km race.
In a coffee-cup calorimeter, 1.60 g NH4NO3 is mixed with 75.0 g water at an initial temperature of 25.00C. After dissolution of the salt, the final temperature of the calorimeter contents is 23.34C. Assuming the solution has a heat capacity of 4.18 J/C g and assuming no heat loss to the calorimeter, calculate the enthalpy change for the dissolution of NH4NO3 in units of kJ/mol.
sample of natural gas is analyzed and found to be88.4% methane (CH4) and 11.6% ethane (C2H6) bymass. The standard enthalpy of combustion of methaneto gaseous carbon dioxide (CO2) and liquid water (H2O) is -891 kJ/mol. Write the equation for the combustionof gaseous ethane to carbon dioxide and water.Calculate the standard enthalpy of combustion of ethaneusing standard enthalpies of formation from Table R-11on page 975. Using that result and the standard enthalpyof combustion of methane in Table 15.3, calculate theenergy released by the combustion of 1 kg of natural gas.
In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both solutions were originally at 24.6C. After the reaction, the final temperature is 31.3C. Assuming that all the solutions have a density of 1.0 g/cm3 and a specific heat capacity of 4.18 J/Cg, calculate the enthalpy change for the neutralization of HCl by NaOH. Assume that no heat is lost to the surroundings or to the calorimeter.
Nitrogen gas (2.75 L) is confined in a cylinder under constant atmospheric pressure (1.01 105 pascals). The volume of gas decreases to 2.10 L when 485 J of energy is transferred as heat to the surroundings. What is the change in internal energy of the gas?
Benzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.
A sample of ethanol, C2H5OH, weighing 2.84 g was burned in an excess of oxygen in a bomb calorimeter. The temperature of the calorimeter rose from 25.00C to 33.73C. If the heat capacity of the calorimeter and contents was 9.63 kJ/C, what is the value of q for burning 1.00 mol of ethanol at constant volume and 25.00C? The reaction is C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) Is q equal to U or H?

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