Answered: 7) Contains C,H,O ketone MASS SPECTRUM…

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter21: Lipids

Section: Chapter Questions

Problem 21.34P

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FOR EACH SPECTRUM BELOW, • IDENTIFY (ASSIGN) THE MOLECULAR ION PEAK AND THE MOLECULAR WT OF THE COMPOUND. ( KEEP IN MIND THAT SOMETIMES THE MOLECULAR ION MAY NOT BE PRESENT, ESPECIALLY FOR LARGE AND BRANCHED CHAIN MOLECULES WITH NO RINGS SINCE THEY CAN FORM STABLE CATION FRAGMENTS) • IDENTIFY THE BASE PEAK AND DRAW STRUCTURE FOR IT ( ASSIGNING THE PEAKS).) • ASSIGN STRUCTURES FOR OTHER PROMINENT FRAGMENTS IF POSSIBLE • BASED ON THIS, SUGGEST A STRUCTURE FOR THE COMPOUND THAT IS CONSISTENT WITH THE DEGREE OF UNSATURATION OF THE COMPOUND INDICATE THE BONDS THAT FRAGMENT, RESULTING IN THE OBSERVED MASS SPECTRAL FRAGMENTS

7) Contains C,H,O ketone
MASS SPECTRUM
100
80
60
40
20
0.0
10
20
30
40
50
60
m/z
NIST Chemistry WebBook (https://webbook.nist.gov/chemistry)
Rel. Intensity
70
80

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