7. a) Identify all the chiral/stereogenic centres in the following molecules. Circle the chiral carbon(s). OH CI -Br CI ОН ČI Br A B OH HO .CI Br HO OH D b) For each chiral center, prioritize the groups (1-4) attached to each chiral center(s) Based on your priorities, assign R or S configurations to the chiral center(s). i) HO H,N° ii) H.. HO, Но OH H. iv) ÕH OH v) H,N-H
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- Build 2‑bromoethan‑1‑ol and its mirror image. 2‑Bromoethan‑1‑ol, which has condensed structural formula BrCH2CH2OH, is also called 2‑bromoethanol. a. Draw the structures of 2‑bromoethan‑1‑ol and its mirror image using wedges and dashed wedges. b. How many stereocentres are present in 2‑bromoethan‑1‑ol? c. Are the molecules chiral? Do they contain planes of symmetry? Briefly explain the evidence for your answer.Specify the configurations (R or S) at ALL chiral centers in the molecules below. Please note that some molecules below may have more than 1 chiral centers, and you are responsible to find all the chiral centers.Using the Cahn-Ingold-Prelog rules, select the option that correctly ranks the priorities for the substituents attached to the chiral center in the molecule below. Note: the highest priority group is labeled as 1, the lowest as 4.
- 4. Subject: -Chemistry indicate which hydrogens are prochiral and give them their correct notation (R or S)a. The specific rotation for pure R is +5.0, what percentage of the mixture is R when the observed roation is -2.0. b. The rotation for pure S=-100. What is the observed rotation of a mixture that is 20%S and 80%R? I need an easy way to solve these kinds of problem, please!!On b), I understand that we don't know which side of the molecule the Cl would attach on, but I was under the impression that we only show stereochemistry on a chiral center, and I do not see where the chiral center is on this molecule. Would you be able to explain this?
- A chiral sample gives a rotation that is close to 180°. How can one tell whether this rotation is +180° or -180°?Most naturally occurring amino acids have chiral centers (the asymmetric a carbon atoms)that are named (S) by the Cahn–Ingold–Prelog convention (Section 5-3). The commonnaturally occurring form of cysteine has a chiral center that is named (R), however.(a) What is the relationship between (R)-cysteine and (S)-alanine? Do they have the oppositethree-dimensional configuration (as the names might suggest) or the same configuration?(b) (S)-Alanine is an l-amino acid (Figure 24-2). Is (R)-cysteine a d-amino acid or anl-amino acid?If the sample of the pure R enantiomer of a molecule has a specific rotation of -40 degrees and your mixture of that molecule has an 82% ee S, what is the observed specific rotation of your sample?
- In each case, assign the correct configuration of R or S, 1 is highest priority, 4 is lowest priority.Compounds with several chiral centres may have configurations referred to as meso. Meso configurations arise when the molecule can adopt a configuration with an internal mirror plane. When this occurs, the mirror image of a molecule with an internal mirror plane is an identical configuration. Thus, even though the molecule may possess several chiral centres, they are reflection of each other (within the molecule) thus resulting in an achiral meso form. This occurs for example for tartaric acid (Figure 3.1). Because of this, tartaric acid only has three stereoisomers instead of four. It has the two chiral (R,R) and (S,S) enantiomers, and the meso form. Figure 3.1. Stereoisomers of tartaric acid. Given the information above on meso forms, how many different stereoisomers do compounds A to D (Figure 3.2) have? Figure 3.2. Structure of compounds A, B, C and D.Organic Chemistry 1 Here is the professor's solution to the problem. However, I do NOT understand the solution. Please explain the answer in a clear step-by-step fashion to me. Explain the answer provided in the image in a clear fashion and as if I did not know much about organic chemistry. It seems to me like the professor is making the problem more complicated than it has to be. Can you demystify or simplify this problem about D glucose? How can you assign priorities on a Fischer projection? I don't get it.