i need the answer quickly 7. Propose a mechanism to account for the formation of products formed bydecomposition of diazocyclodecane in the following reaction.N2H.-N2H.H.62%14%6%18%8. Write a suitable mechanism for the following transformations.CHCI3(i)BaseCHCI2(ii)R.cat. Rh2+CHOhv, MeOH(iii)O:O.THFN2CO,MeN3Heat(iv)NH2TolueneCO,Mehv, MeOH(v)

Diazo compound is subject to light, nitrogen is eliminated and carbene is generated. Carbene is…

7. Propose a mechanism to account for the formation of products formed by decomposition of diazocyclodecane in the following reaction. N2 H. H H + + 18% 62% 14% 6% 8. Write a suitable mechanism for the following transformations. CHCI3 (i) Base CHCI2 H R (ii) cat. Rh2+ R N2 CHO hv, MeOH (ii) O: THF CO,Me N3 Heat (iv) NH2 Toluene hv, MeOH CO2M (v)

7. Propose a mechanism to account for the formation of products formed by decomposition of diazocyclodecane in the following reaction. N2 H. H H + + 18% 62% 14% 6% 8. Write a suitable mechanism for the following transformations. CHCI3 (i) Base CHCI2 H R (ii) cat. Rh2+ R N2 CHO hv, MeOH (ii) O: THF CO,Me N3 Heat (iv) NH2 Toluene hv, MeOH CO2M (v)

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 6CTQ

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In this study, the researcher compared S N 2 and E2reaction rates for four substrates. Three of the substrates had a second halogen on the bposition in the molecule. This work also compared the behavior of two nucleophiles:dianion I and II. You should read the abstract and look at Scheme 1 (p. 3082) and Table 4(p. 3086). Abstract: The gas-phase reactions of benzoate and phenolate containing dianions with a series of ‚-substitutedalkyl bromides (X-CH2CH2Br, X ) H, F, Cl, Br) have been studied in a quadrupole ion trap mass spectrometer.Branching ratios between SN 2 and E2 products were measured and rate constants were determined. The‚-halogens increase both the S N 2 and E2 rates, but the effect is greater for the latter process and thereforethese substituents lead to an increase in the amount of elimination. The kinetic data for the SN 2 reactions canbe analyzed via a two-parameter, linear free-energy relationship and the results indicate that field-effects (i.e.,electron-withdrawing…
In this study, the researcher compared S N 2 and E2reaction rates for four substrates. Three of the substrates had a second halogen on the bposition in the molecule. This work also compared the behavior of two nucleophiles:dianion I and II. You should read the abstract and look at Scheme 1 (p. 3082) and Table 4(p. 3086). Abstract: The gas-phase reactions of benzoate and phenolate containing dianions with a series of ‚-substitutedalkyl bromides (X-CH2CH2Br, X ) H, F, Cl, Br) have been studied in a quadrupole ion trap mass spectrometer.Branching ratios between SN 2 and E2 products were measured and rate constants were determined. The‚-halogens increase both the S N 2 and E2 rates, but the effect is greater for the latter process and thereforethese substituents lead to an increase in the amount of elimination. The kinetic data for the SN 2 reactions canbe analyzed via a two-parameter, linear free-energy relationship and the results indicate that field-effects (i.e.,electron-withdrawing…
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