8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H +0.989,,, C where is the (normalized) hydrogen 1s orbital and , a is the (normalized) chlorine 3pz orbital. Assume that the atomic overlap integral is zero, YW3P.cdt =0. all space a) Show that the bonding molecular orbital is normalized. b) What is the energy of the bonding orbital? Write your answer in terms of a,,a,, and B, which are defined by: S Wop,ci Hwdr = ß all space all space %3D | Vis. Hyudt = a, and ] Wap.c Hwap.cd7 = d;p. %3D | V1s,H all space all space
8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H +0.989,,, C where is the (normalized) hydrogen 1s orbital and , a is the (normalized) chlorine 3pz orbital. Assume that the atomic overlap integral is zero, YW3P.cdt =0. all space a) Show that the bonding molecular orbital is normalized. b) What is the energy of the bonding orbital? Write your answer in terms of a,,a,, and B, which are defined by: S Wop,ci Hwdr = ß all space all space %3D | Vis. Hyudt = a, and ] Wap.c Hwap.cd7 = d;p. %3D | V1s,H all space all space
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter12: The Solid State
Section: Chapter Questions
Problem 19PS: Considering only the molecular orbitals formed by combinations of the 2s atomic orbitals, how many...
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