8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H +0.989,,, C where is the (normalized) hydrogen 1s orbital and , a is the (normalized) chlorine 3pz orbital. Assume that the atomic overlap integral is zero, YW3P.cdt =0. all space a) Show that the bonding molecular orbital is normalized. b) What is the energy of the bonding orbital? Write your answer in terms of a,,a,, and B, which are defined by: S Wop,ci Hwdr = ß all space all space %3D | Vis. Hyudt = a, and ] Wap.c Hwap.cd7 = d;p. %3D | V1s,H all space all space

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter12: The Solid State
Section: Chapter Questions
Problem 19PS: Considering only the molecular orbitals formed by combinations of the 2s atomic orbitals, how many...
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8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by,
citation
legg
W, = 0.205,H +0.98º3p,cI
%D
ght ventric
FULL PRIC
where ø is the (normalized) hydrogen 1s orbital and o,, c is the (normalized) chlorine
BOG
3pz orbital. Assume that the atomic overlap integral is zero, | WisH W3p.cadt = 0.
%3D
all space
a) Show that the bonding molecular orbital is normalized.
Shot
232 PM
BOO
and B,
b) What is the energy of the bonding orbital? Write your answer in terms of a,, ,a,,.
T COS
which are defined by:
АМ
Shbt
25PM
ght ventric
| V1s,H
Hw cdt = |
4 1s,H
RENT &
||
all space
all space
Che
pulmc
vein
| Wis.H HySHdt =a,, and
cdt = d3p.
1s,
3 Pz,CI
right
atriursen Shot
2021-02 5.56 PM
pulmonary
valve
all space
all space
W
étv A
APR 4
29
260
Book A
DD
F11
F10
Transcribed Image Text:8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, citation legg W, = 0.205,H +0.98º3p,cI %D ght ventric FULL PRIC where ø is the (normalized) hydrogen 1s orbital and o,, c is the (normalized) chlorine BOG 3pz orbital. Assume that the atomic overlap integral is zero, | WisH W3p.cadt = 0. %3D all space a) Show that the bonding molecular orbital is normalized. Shot 232 PM BOO and B, b) What is the energy of the bonding orbital? Write your answer in terms of a,, ,a,,. T COS which are defined by: АМ Shbt 25PM ght ventric | V1s,H Hw cdt = | 4 1s,H RENT & || all space all space Che pulmc vein | Wis.H HySHdt =a,, and cdt = d3p. 1s, 3 Pz,CI right atriursen Shot 2021-02 5.56 PM pulmonary valve all space all space W étv A APR 4 29 260 Book A DD F11 F10
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