8) Indicate the MAJOR product for each of the following reactions: OH CH3I (excess) HO OH Ag₂O (functions as mild base) 1) HCN 2) H₂/Pd/BaSO4/ H₂O 1) NH₂OH 2) Ac₂0 3) NaOCH3 HO H. O HO -H H -OH HO H -OH CH₂OH -OH H₂ I H- HO-H OH CH3 (HINT: Kiliani-Fischer Synthesis) (Hint: Wohl Degradation)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter9: Addition Via Cyclic Intermediate
Section: Chapter Questions
Problem 2E
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8) Indicate the MAJOR product for each of the following reactions:
OH
CH3I (excess)
HO
OH
Ag₂O (functions as mild base)
1) HCN
2) H₂/Pd/BaSO4/ H₂O
1) NH₂OH
2) Ac₂0
3) NaOCH3
HO
H. O
HO
-H
H -OH
HO
H
-OH
CH₂OH
-OH
H₂
I
H-
HO-H
OH
CH3
(HINT: Kiliani-Fischer Synthesis)
(Hint: Wohl Degradation)
Transcribed Image Text:8) Indicate the MAJOR product for each of the following reactions: OH CH3I (excess) HO OH Ag₂O (functions as mild base) 1) HCN 2) H₂/Pd/BaSO4/ H₂O 1) NH₂OH 2) Ac₂0 3) NaOCH3 HO H. O HO -H H -OH HO H -OH CH₂OH -OH H₂ I H- HO-H OH CH3 (HINT: Kiliani-Fischer Synthesis) (Hint: Wohl Degradation)
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