A 25.0 mL sample of 0.100 M acetic acid is titrated with 0.125 M NaOH . What is the pH of the solution after 20.0 mL of NaOH have need added? (Hint: What is in solution after the addition of the NaOH?)

General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.88QP: A 0.400-g sample of propionic acid was dissolved in water to give 50.0 mL of solution. This solution...
icon
Related questions
Question

A 25.0 mL sample of 0.100 M acetic acid is titrated with 0.125 M NaOH . What is the pH of the solution after 20.0 mL of NaOH have need added? (Hint: What is in solution after the addition of the NaOH?)

Expert Solution
Introduction

If any base (strong base) gets added into weak acid then buffer solution formation occurs in which salt gets yielded as formed species. This solution posses specific pH depending over the volume/concentration of acid-base. This solution's alkalinity or acidity gets expressed by its "pH".

 

 

Given

The volume of acetic acid is 25.0 mL.

The concentration of acetic acid is 0.100 M.

The concentration of NaOH is 0.125 M.

The volume of NaOH is 20.0 mL.

Solution

The reaction for the formation of sodium acetate is shown below.

Chemistry homework question answer, step 2, image 1

Calculation of the pH on adding 20.0 mL of NaOH is added.

The number of moles of acetic acid can be calculated as shown below.

Chemistry homework question answer, step 2, image 2

Similarly, the number of moles of NaOH is calculated can be calculated as shown below.

Chemistry homework question answer, step 2, image 3

Solution

The ICE table is thus shown below.

Chemistry homework question answer, step 3, image 1

Thus the solution is formed will be buffer.

Since the number of moles of NaOH is equal to the number of moles of acetic acid. This indicates that the solution is reached at the endpoint.

At endpoint, acid, as well as base, get completely consumed in the reaction to form sodium acetate.

The total volume of solution can be calculated as shown below

 (25.0+20.0) mL=45 mL.

steps

Step by step

Solved in 6 steps with 8 images

Blurred answer
Knowledge Booster
Acid-Base Titrations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
General Chemistry - Standalone book (MindTap Cour…
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry for Today: General, Organic, and Bioche…
Chemistry for Today: General, Organic, and Bioche…
Chemistry
ISBN:
9781305960060
Author:
Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:
Cengage Learning
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax