A 30.0 mL solution of 0.0180 M Rh3+ in 1 M HClO4 was titrated with 0.0900 M Ce4+ to give Rh6+ and Ce3+. Calculate the potential (vs. Ag | AgCl) at the equivalence point. At what volume of titrant will the potential be equal to the standard potential of the Ce half-reaction (ignoring the Ag | AgCl electrode)?

Chemistry: The Molecular Science
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Chapter17: Electrochemistry And Its Applications
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A 30.0 mL solution of 0.0180 M Rh3+ in 1 M HClO4 was titrated with 0.0900 M Ce4+ to give Rh6+ and Ce3+.

Calculate the potential (vs. Ag | AgCl) at the equivalence point.

At what volume of titrant will the potential be equal to the  standard potential of the Ce half-reaction (ignoring the Ag | AgCl electrode)?

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