A 4000 3000 2000 1500 1000 0.8- 0.6 0.4 0.2 3000 2000 1000 Transmittance% 100 50- C 4000 3000 2500 2000 1500 -1 1000 500 Wavenumbers / em Figure 1. IR spectra A, B and C

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter12: Infrared Spectroscopy
Section: Chapter Questions
Problem 12.6P: Following are infrared spectra of nonane and 1-hexanol. Assign each compound its correct spectrum.
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1a) Draw the keto-enol equilibrium reaction for the following ketone

1b) Figure 1 shows three IR spectra, labelled A, B and C. Identify which one corresponds to the ketone shown in section 1a). Justify your answer by discussing the appropriate bands of the three spectra.

A
4000
3000
2000
1500
1000
0.8-
0.6-
0.4-
B
0.2
3000
2000
1000
Transmittance%
100
50
C
4000
3000
2500
2000
1500
1000
500
Wavenumbers / cm
Figure 1. IR spectra A, B and C
Transcribed Image Text:A 4000 3000 2000 1500 1000 0.8- 0.6- 0.4- B 0.2 3000 2000 1000 Transmittance% 100 50 C 4000 3000 2500 2000 1500 1000 500 Wavenumbers / cm Figure 1. IR spectra A, B and C
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