A common misconception about vapor pressure lowering is that the solute occupies some of the surface sites in the solution, reducing the percentage of solvent molecules that can potentially overcome the attractive intermolecular forces and transition into the gas phase. (a) Draw a particulate-level sketch of a nonvolatile molecular solute in water and use it to explain why the misconception is incorrect. (b) What is the correct explanation for vapor pressure lowering?

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter10: Properties Of Solutions
Section: Chapter Questions
Problem 5ALQ: You have read that adding a solute to a solvent can both increase the boiling point and decrease the...
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A common misconception about vapor pressure lowering is that the solute occupies some of the surface sites in the solution, reducing the percentage of solvent molecules that can potentially overcome the attractive intermolecular forces and transition into the gas phase. (a) Draw a particulate-level sketch of a nonvolatile molecular solute in water and use it to explain why the misconception is incorrect. (b) What is the correct explanation for vapor pressure lowering?

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