A deoxyhemoglobin molecule (molar mass 65,000 g) can bind up to four oxygen molecules. In a certain experiment a 0.065 L solution containing 6.3 g of deoxyhemoglobin (hemoglobin without oxygen molecules bound to it) was reacted with an excess of oxygen in a constant pressure calorimeter of negligible heat capacity. Calculate the enthalpy of reaction per mole of oxygen bound if the temperature rose by 0.011°C. Assume that the density of the solution is 1.00 g/mL and that the heat capacity of the solution is the same as the specific heat of water, 4.184 J/gºC.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter6: Thermochemistry
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Problem 127CWP: In a coffee-cup calorimeter, 150.0 mL of 0.50 M HCI is added to 50.0 mL of 1.00 M NaOH to make 200.0...
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A deoxyhemoglobin molecule (molar mass 65,000 g) can bind up to four oxygen molecules. In a certain experiment a 0.065 L solution containing 6.3 g of deoxyhemoglobin (hemoglobin without oxygen molecules bound to it) was reacted with an excess of oxygen in a constant pressure calorimeter of negligible heat capacity. Calculate the enthalpy of reaction per mole of oxygen bound if the temperature rose by 0.011°C. Assume that the density of the solution is 1.00 g/mL and that the heat capacity of the solution is the same as the specific heat of water, 4.184 J/gºC.

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