A galvanic cell is powered by the following redox reaction: 5 Cl,(9) + I,(s) + 6 H,O(1) - 10 Cl (aq) + 2 IO,(aq) + 12 H"(aq) Answer the following questions about this cell. If you need any electrochemical data, be sure you get it from the ALEKS Data tab. O-0 Write a balanced equation for the half-reaction that takes place at the cathode. Write a balanced equation for the half-reaction that takes place at the anode. Calculate the cell voltage under standard conditions. E° = Ov Round your answer to 2 decimal places.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 14P
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A galvanic cell is powered by the following redox reaction:
5 Cl,(9) + I2(s) + 6 H2O(1)
- 10 CI (aq) + 2 IO,(aq) + 12 H"(aq)
Answer the following questions about this cell. If you need any electrochemical data, be sure you get it from the ALEKS Data tab.
Write a balanced equation for
the half-reaction that takes
place at the cathode.
Write a balanced equation for
the half-reaction that takes
place at the anode.
Calculate the cell voltage
under standard conditions.
E° = [ v
Round your answer to 2
decimal places.
lo
Transcribed Image Text:A galvanic cell is powered by the following redox reaction: 5 Cl,(9) + I2(s) + 6 H2O(1) - 10 CI (aq) + 2 IO,(aq) + 12 H"(aq) Answer the following questions about this cell. If you need any electrochemical data, be sure you get it from the ALEKS Data tab. Write a balanced equation for the half-reaction that takes place at the cathode. Write a balanced equation for the half-reaction that takes place at the anode. Calculate the cell voltage under standard conditions. E° = [ v Round your answer to 2 decimal places. lo
Half-Reaction
E° (V)
2H+ (aq) + 2e¯ → H2 (g)
0.000
Ag* (aq) + e¯ → Ag (s)
0.7996
2H20 (1) + 2e¯ - H2 (g) + 20H¯ (aq)
-0.8277
AI3+ (aq) + 3e¯ → Al (s)
-1.676
H202 (aq) + 2H* (aq) + 2e¯ → 2H20 (I)
1.776
Au+ (aq) + e¯→ Au (s)
1.692
I2 (s) + 2e- → 21¯ (aq)
0.5355
Au3+ (aq) + 3e¯ → Au (s)
1.498
Ba2+ (aq) + 2e¯ → Ba (s)
2103- (aq) + 12H* (aq) + 10e¯ → I2 (s) + 6H2O (1)
1.195
-2.912
Mg2+ (aq) + 2e¯ → Mg (s)
-2.372
Brz (1) + 2e¯ → 2Br¯ (aq)
1.066
Mn2+ (aq) + 2e¯ → Mn (s)
-1.185
Ca2+ (aq) + 2e¯ → Ca (s)
-2.868
MnO2 (s) + 4H+ (aq) + 2e¯ → Mn2+ (aq) + 2H20 (I)
1.224
Cl2 (g) + 2e¯ → 2C1¯ (aq)
1.35827
Mno4- (aq) + 8H+ (aq) + 5e¯ → Mn2+ (aq) + 4H20 (1)
1.507
Co2+ (aq) + 2e¯ → Co (s)
-0.28
Mn04 (aq) + 2H2O (I) + 3e¯ → MnO2 (s) + 40H¯ (aq)
0.595
Co3+ (aq) + e¯ → Co2+ (aq)
Cr2+ (aq) + 2e- → Cr (s)
1.92
HNO2 (aq) + H+ (aq) + e¯ → NO (g) + H2O (I)
0.983
-0.913
N2 (g) + 4H20 (1) + 4e¯ → 40H" (aq) + N½H4 (aq)
-1.16
Cr3+ (aq) + 3e¯ → Cr (s)
Cr3+ (aq) + e- → Cr2+ (aq)
-0.744
NO3- (aq) + 4H* (aq) + 3e¯ → NO (g) + 2H2O (1)
0.957
-0.407
Na+ (aq) + e - Na (s)
-2.71
Cro42- (aq) + 4H20 (I) + 3e¯ → Cr(OH)3 (s) + 50H" (aq)
-0.13
Ni2+ (aq) + 2e¯ → Ni (s)
-0.257
Cu2+ (aq) + 2e¯ → Cu (s)
0.3419
02 (g) + 4H* (aq) + 4e¯ → 2H20 (1)
1.229
Cu2+ (aq) + e- → Cu* (aq)
0.153
02 (g) + 2H20 (1) + 4e¯ → 40OH" (aq)
0.401
Cu* (aq) + e¯ → Cu (s)
0.521
02 (g) + 2H+ (aq) + 2e¯ → H2O2 (aq)
0.695
F2 (g) + 2e¯ → 2F¯ (aq)
2.866
Pb2+ (aq) + 2e - Pb (s)
-0.1262
Fe2+ (aq) + 2e¯ → Fe (s)
-0.447
PBSO4 (s) + H+ (aq) + 2e¯ → Pb (s) + HSO4 (aq)
-0.3588
Fe3+ (aq) + e¯ → Fe2+ (aq)
0.771
HSO4- (aq) + 3H+ (aq) + 2e¯ → H2SO3 (aq) + H20 (1)
0.172
Fe3+ (aq) + 3e¯ → Fe (s)
-0.037
Sc3+ (aq) + 3e - Sc (s)
-2.077
Sn2+ (aq) + 2e¯
Sn (s)
-0.1375
Sn4+ (aq) + 2e¯ →
Sn²+ (aq)
0.151
vo2+ (aq) + 2H+ (aq) + e¯ → vo2+ (aq) + H2O (1)
0.991
Zn2+ (aq) + 2e¯
- Zn (s)
-0.7618
Transcribed Image Text:Half-Reaction E° (V) 2H+ (aq) + 2e¯ → H2 (g) 0.000 Ag* (aq) + e¯ → Ag (s) 0.7996 2H20 (1) + 2e¯ - H2 (g) + 20H¯ (aq) -0.8277 AI3+ (aq) + 3e¯ → Al (s) -1.676 H202 (aq) + 2H* (aq) + 2e¯ → 2H20 (I) 1.776 Au+ (aq) + e¯→ Au (s) 1.692 I2 (s) + 2e- → 21¯ (aq) 0.5355 Au3+ (aq) + 3e¯ → Au (s) 1.498 Ba2+ (aq) + 2e¯ → Ba (s) 2103- (aq) + 12H* (aq) + 10e¯ → I2 (s) + 6H2O (1) 1.195 -2.912 Mg2+ (aq) + 2e¯ → Mg (s) -2.372 Brz (1) + 2e¯ → 2Br¯ (aq) 1.066 Mn2+ (aq) + 2e¯ → Mn (s) -1.185 Ca2+ (aq) + 2e¯ → Ca (s) -2.868 MnO2 (s) + 4H+ (aq) + 2e¯ → Mn2+ (aq) + 2H20 (I) 1.224 Cl2 (g) + 2e¯ → 2C1¯ (aq) 1.35827 Mno4- (aq) + 8H+ (aq) + 5e¯ → Mn2+ (aq) + 4H20 (1) 1.507 Co2+ (aq) + 2e¯ → Co (s) -0.28 Mn04 (aq) + 2H2O (I) + 3e¯ → MnO2 (s) + 40H¯ (aq) 0.595 Co3+ (aq) + e¯ → Co2+ (aq) Cr2+ (aq) + 2e- → Cr (s) 1.92 HNO2 (aq) + H+ (aq) + e¯ → NO (g) + H2O (I) 0.983 -0.913 N2 (g) + 4H20 (1) + 4e¯ → 40H" (aq) + N½H4 (aq) -1.16 Cr3+ (aq) + 3e¯ → Cr (s) Cr3+ (aq) + e- → Cr2+ (aq) -0.744 NO3- (aq) + 4H* (aq) + 3e¯ → NO (g) + 2H2O (1) 0.957 -0.407 Na+ (aq) + e - Na (s) -2.71 Cro42- (aq) + 4H20 (I) + 3e¯ → Cr(OH)3 (s) + 50H" (aq) -0.13 Ni2+ (aq) + 2e¯ → Ni (s) -0.257 Cu2+ (aq) + 2e¯ → Cu (s) 0.3419 02 (g) + 4H* (aq) + 4e¯ → 2H20 (1) 1.229 Cu2+ (aq) + e- → Cu* (aq) 0.153 02 (g) + 2H20 (1) + 4e¯ → 40OH" (aq) 0.401 Cu* (aq) + e¯ → Cu (s) 0.521 02 (g) + 2H+ (aq) + 2e¯ → H2O2 (aq) 0.695 F2 (g) + 2e¯ → 2F¯ (aq) 2.866 Pb2+ (aq) + 2e - Pb (s) -0.1262 Fe2+ (aq) + 2e¯ → Fe (s) -0.447 PBSO4 (s) + H+ (aq) + 2e¯ → Pb (s) + HSO4 (aq) -0.3588 Fe3+ (aq) + e¯ → Fe2+ (aq) 0.771 HSO4- (aq) + 3H+ (aq) + 2e¯ → H2SO3 (aq) + H20 (1) 0.172 Fe3+ (aq) + 3e¯ → Fe (s) -0.037 Sc3+ (aq) + 3e - Sc (s) -2.077 Sn2+ (aq) + 2e¯ Sn (s) -0.1375 Sn4+ (aq) + 2e¯ → Sn²+ (aq) 0.151 vo2+ (aq) + 2H+ (aq) + e¯ → vo2+ (aq) + H2O (1) 0.991 Zn2+ (aq) + 2e¯ - Zn (s) -0.7618
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