A recent article reported that benzylic bromination can be achieved photochemically using bromotrichloromethane as the brominating agent (you used NBS in lab) as shown below. Draw the mechanism of this reaction, labeling all sets as either "Initiation" or "Propagation". Also, show one feasible termination step. Helpful BDE's are given. How many unique hydrogens (NMR) are present in the product? Br Org. Biomol. Chem. 2019, 17, 1384 BrCCl3 hv Мео OMe Мео OMe OMe ОMe BDE of C-Br bond ~230 kJ/mol BDE of C-H in HCClg~ 401 kJ/mol

A recent article reported that benzylic bromination can be achieved photochemically using bromotrichloromethane as the brominating agent (you used NBS in lab) as shown below. Draw the mechanism of this reaction, labeling all sets as either "Initiation" or "Propagation". Also, show one feasible termination step. Helpful BDE's are given. How many unique hydrogens (NMR) are present in the product? Br Org. Biomol. Chem. 2019, 17, 1384 BrCCl3 hv Мео OMe Мео OMe OMe ОMe BDE of C-Br bond ~230 kJ/mol BDE of C-H in HCClg~ 401 kJ/mol

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 30CTQ

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