Show by means of labels, drawings, and atom position change, the following symmetry operationsA C4 rotation (use clockwise rotation) followed by an inversion on square planar [PtCl4]2-A rotation about a Cz axis that is perpendicular to the C4 principal axis on square planar [PtCl4]2-How many planes of symmetry does square planar [PtCl4]2- have? Identify them on the drawing.Label as appropriate σh , σv

Answered: Image /qna-images/answer/f2a7b321-7a8f-4e52-92cd-72b709b388dc.jpg

A rotation about a Cz axis that is perpendicular to the C4 principal axis on square planar [PtCl4]2- How many planes of symmetry does square planar [PtCl4]2- have? Identify them on the drawing. Label as appropriate σh , σv

A rotation about a Cz axis that is perpendicular to the C4 principal axis on square planar [PtCl4]2- How many planes of symmetry does square planar [PtCl4]2- have? Identify them on the drawing. Label as appropriate σh , σv

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

ChapterL3: Carbon (13c) Nmr Spectroscopy

Section: Chapter Questions

Problem 1E

See similar textbooks

Related questions

Q: gu configura an S configuratic has an S configuration, r hat are the configurations around the CH3 d…

A: We have to tell that what E/Z configuration given compounds are exhibiting

Q: 2. Use as a basis the valence pz orbitals on each atom in BF3 to a. Find the matrix representative…

Q: Draw the new Molecular orbital energy diagram for [Co(NH3)5(H2O)]3+, indicating the symmetry…

A: (Co(NH3)5H2O)+3 is a coordination compound whose IUPAC name is pentaammineaquacobalt It is an…

Q: XeF4 A CIA B SIF4.C Which molecule does not have (tetrahedral ) Td symmetry? GeH4 D

Q: Which of the following molecules contain stereocenters (asymmetric C atoms)? Choose all that apply.…

Q: 3. Assign each molecule or ion to its proper point group. a. XeO6(perxenate) b. BrFs c.…

Q: draw all the possible phasing combination for the conpound [Ir(H)6]3- for the 6s orbital being…

Q: The_isomer of [Fe(NH3)3CI3] has C2y symmetry. mer fac

A: Welcome to bartleby!

Q: f. OH H. .CH3 H3C H. Br

A: This is newnans projection structure, for easy way find the absolut configuration for asymmetri…

Q: Directions: Based on your understanding of the effects of molecular symmetry on the polarity of a…

A: The molecules given are,

Q: The complete set of symmetry elements in PCI5 are: Select one: O E, C3, 3C2, ơh, S3 and 30y O E, C3,…

Q: Select the species that contain an inversion center. SF6 BCI, O (IF.) SnH4

A: If the molecule represents an indistinguishable configuration even when the co-ordinates(x,y,z) of…

Q: Which of the following molecules are diamagnetic: H2+1, H2, H2-1, H2-2?

A: The species will be the diamagnetic in nature if they have paired electrons.

Q: (b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have:…

A: Symmetry elements are the topological operation in which exchange of the identical atoms takes place…

Q: What is the symmetry of a C 2pz orbital in tetrahedral CH4? а 1 e t 2 O t1

A: This can be describe through character table. Total symmetric is A1 and C2pz ,C2px , C2py are T2…

Q: Draw the new Molecular orbital energy diagram for [Co(NH3)5(H2O)]3+, indicating the symmetry…

A: To draw the molecular orbital energy diagram for [Co(NH3)5H2O]3+ indicating the symmetry designation…

Q: QUESTION TWO (i) Find the highest n-fold rotation axis for each of the following species: (a) (b)…

Q: Benzene ring has only one s6 symmetry but 6c2 in addition to other symmetry elements True False

A: The ‘s’notation symbolizes improper axis of symmetry which includes an axis of symmetry followed by…

Q: но HO OH HO Br HO Br %| II IV

A: Plane of symmetry sigma plane is an imaginary plane present in a molecule which bisects the molecule…

Q: H OCH3 HOH2C "СООН

A: Given structure is : Determine whether it has the (R) or (S) configuration = ?

Q: Set up the secular determinants for (i) azulene (3), (ii) acenaphthylene (4) within the Hückel…

A: (i) azulene The secular determinant for azulene is set within Huckel approximation as shown below,…

Q: r=−4sinθ+4cosθ+4θ Which of the following types of symmetry is demonstrated in the equation above…

A: Given, r = − 4sinθ + 4cosθ + 4θ We have to show the types of symmetry is demonstrated in…

Q: 9. How many stereo centres are there in the following molecule?

Q: Which of the following has the S4 rotation-reflection axis? A. C2H2 B. BF3 C. CH4 D. CO2 E.…

A: The S4 axis of symmetry signifies rotation through a central axis by 90o followed by reflection…

Q: Which of the following symmetry elements is not correct for C6H6 ? C4.A O C2.B O C3.cO C6.DO

A: The question is based on the concepts of group theory. we need to identify the symmetry element…

Q: Based on the symmetry considerations used for homonucelar diatomic molecules, consider the C2H4 a.…

A: When symmetry of two orbitals matches, then bonding orbitals are formed. When symmetry of two…

Q: Determine the major axis of symmetry for the following 2-dimensional shape: (A) C2 (В) С, (С) C, (D)…

A: Major axis are those which have highest oneo Order (n) =360 o /rotating angle Axis of symmetry…

Q: Please answer and explain.

A: The proper axis of rotation is the rotation of the molecule with respect to a certain axis. For the…

Q: C2H4: HOMO-1 ole C2H2: HOMO ng ond Sond C2H2: HOMO–1 o pais ng eis C2H2: HOM0-2 regativj momeut ch…

A: Solution Given that C2H4: HOMO - 1 C2H2: HOMO C2H2: HOMO - 1 C2H2: HOMO…

Q: Directions: Based on your understanding of the effects of molecular symmetry on the polarity of a…

A: When electrons are attracted to one side then the molecule will be polar.

Q: Q 1.7: Ethene, H. , has a total of pi antibonding molecula C=C, H. H A B C 3 E 4 2.

A: Molecular orbitals are formed by the linear combination of atomic orbitals which results into…

Q: • Due to the delocalization of electrons in the ring, where the bond order between carbons is 1 ½,…

A: I have taken the example of benzene .

Q: S4 rotation-reflection axis

Q: Benzene ring has only one S6 symmetry but bC2 in addition to other symmetry elements True False

A: Benzene belongs to D6h point group.

Q: 13. How many molecules/ions below have an inversion center (i)? A. 0 В. 1 С. 2 D. 3 E. 4

Q: 3) Reduce the following representations into its corresponding reducible representations: a) Under…

Q: OH OH 214 O O + CICH₂Br K₂CO3 218 O Which of the following symmetry operations are present in the…

A: Answer. Symmetry elements are geometrical operations to obtain symmetry. Various symmetry…

Q: (a) Identify the principal (z) rotational axis for all molecules provided below. (b) Provide a…

A: Symmetry operation is an action perfomed on a molecule , yields an new orientation of it that is…

Q: The complete set of symmetry elements in CHC13 are: Select one: O E, C3, 30y O C3, 30v, S3 O E, C3,…

Q: Do these molecules has centre of symmetry(C.O.S)? If not,why? If we draw lines passing through the…

A: If an imaginary plane is passed to the any point of the surface through the center and a similar…

Q: A sample of a pure liquid with a density of 0.79 g/mL has an observed rotation of 113.8, what is the…

A: The expression for specific rotation is as follows, αD = αl c Where, αD =…

Q: (a) Draw the orbital picture for :C=0: showing the explicit overlap of the contributing AOs. (b) How…

A: Molecular orbitals are formed by the Linear Combination of Atomic Orbitals (LCAO). Number of…

Q: (H2S2). These are trans (dihedral angle is 180), cis (dihedral angle is 0), and skew (any…

Q: 1. Where are the symmetrical classifcations on the molecules? 2. What is the point group for each…

A: Following are the symmetrical classification, point group and chirality of the given compounds.

Q: Use as a basis the valence pz orbitals on each atom in BF3 to Find the matrix representative of…

Q: 3. Assign each molecule or ion to its proper point group. a. cyclopropylene b. aziridine (hint: be…

A: First draw the structure of the compound Then determine the number of symmetry elements present in…

Question

Show by means of labels, drawings, and atom position change, the following symmetry operations
A C₄ rotation (use clockwise rotation) followed by an inversion on square planar [PtCl₄]^2-
A rotation about a C_z axis that is perpendicular to the C₄ principal axis on square planar [PtCl₄]^2-
How many planes of symmetry does square planar [PtCl₄]^2- have? Identify them on the drawing.

Label as appropriate σ_h, σ_v

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Answer

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.
1- Draw the open structures of the following molecules and examine them in terms of whether they have an inversion center (i) and a rotation-reflection process (Sn). a) CO2 b) C2H2 c) BF3 d) PCl3 e) PCl5
draw all the possible phasing combination for the conpound [Ir(H)6]3- for the 6s orbital being surrounded by 6 1s hydrogen orbitals. for example) fully bonded in phase representation (shown below)
Which of the following has the S4 rotation-reflection axis? A. NH3 B. CH4 C. BF3 D. C2H2 e.CO2
Which of these is the correct rotation for [a] of 0°?
(b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i) C4 (ii) σh (iii) S4
2. We can form a group of symmetry operations, with our operation being do one operation and do another. For a molecule with an isosceles triangle molecule like water, we talked about the 4 symmetry operations as E (do nothing), C2 (rotation by 180°), σv (the reflection of one hydrogen to the other), and σv’ (the reflection from front to back). By putting coordinates on each of the three atoms (z points along the C2 rotation axis, x points from one hydrogen to the other, and y points out of the plane of the molecule) find the “multiplication” table for this group.
2. Use as a basis the valence pz orbitals on each atom in BF3 to a. Find the matrix representative of the operation C3. Take z as perpendicular to the molecular plane and C3 as counterclockwise rotation.b. find the character of the matrix representative for C3.
The molecule of interest PtCl4^2-. Find the irreducible representation(s) of the pz orbitals, using the pz orbitals of Cl. Also, use the projection operator method and show what one irreducible representation looks like. What orbitals if any match up with the orbital on Pt (from a pure symmetry approach)
Benzene ring has only one s6 symmetry but 6c2 in addition to other symmetry elements TrueFalse
Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i) C4 (ii) σh (iii) S4.
Make a list of all symmetry operations present in Bh3 and H2O?