A solution containing a mixture of metal cations was treated as follows. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H, S was bubbled through the acidic solution. Again, a precipitate formed and was filtered off. 3. The pH was raised to about 9 and H, S was again bubbled through the solution. No precipitate formed. 4. Finally, sodium carbonate was added and no precipitate formed. What can be said about the presence of each of these groups of cations in the original solution?

Chemistry: The Molecular Science
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Chapter19: The Chemistry Of The Main-group Elements
Section: Chapter Questions
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Ag*, Pbt, Hg5*
form insoluble chlorides
Bi3+, Cd2+, Cu²+, Hg²+,
Pb2+, Sb³+, Sn²+, Sn+
form acid-insoluble sulfides
Al3+, Co2+, Cr³+, Fe2+,
Fe3+, Ni²+, Mn²+, Zn²+
form base-insoluble sulfides or hydroxides
Ba?+, Ca?+, Mg²+, Sr²+
form insoluble carbonates
Lit, Na*, K*, NH
completely soluble
Answer Bank
All of these ions were present.
unknown
None of these ions were present.
At least one of these ions was present.
Transcribed Image Text:Ag*, Pbt, Hg5* form insoluble chlorides Bi3+, Cd2+, Cu²+, Hg²+, Pb2+, Sb³+, Sn²+, Sn+ form acid-insoluble sulfides Al3+, Co2+, Cr³+, Fe2+, Fe3+, Ni²+, Mn²+, Zn²+ form base-insoluble sulfides or hydroxides Ba?+, Ca?+, Mg²+, Sr²+ form insoluble carbonates Lit, Na*, K*, NH completely soluble Answer Bank All of these ions were present. unknown None of these ions were present. At least one of these ions was present.
A solution containing a mixture of metal cations was treated as follows.
1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off.
2. H, S was bubbled through the acidic solution. Again, a precipitate formed and was filtered off.
3. The pH was raised to about 9 and H, S was again bubbled through the solution. No precipitate formed.
4. Finally, sodium carbonate was added and no precipitate formed.
What can be said about the presence of each of these groups of cations in the original solution?
Cation Group
Description
Present in the original solution?
Ag+, Pb?+, Hgž+
form insoluble chlorides
Bit, Cd²+, Cu²+, Hg²+,
Pb2+, Sb3+, Sn²+, Sn+
form acid-insoluble sulfides
Al3+, Co2+, Cr+, Fe²+,
Fe3+, Ni2+, Mn2+, Zn2+
form base-insoluble sulfides or hydroxides
Ba?+, Ca?+, Mg²+, S²+
form insoluble carbonates
Lit, Nat, K+, NH
completely soluble
Transcribed Image Text:A solution containing a mixture of metal cations was treated as follows. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H, S was bubbled through the acidic solution. Again, a precipitate formed and was filtered off. 3. The pH was raised to about 9 and H, S was again bubbled through the solution. No precipitate formed. 4. Finally, sodium carbonate was added and no precipitate formed. What can be said about the presence of each of these groups of cations in the original solution? Cation Group Description Present in the original solution? Ag+, Pb?+, Hgž+ form insoluble chlorides Bit, Cd²+, Cu²+, Hg²+, Pb2+, Sb3+, Sn²+, Sn+ form acid-insoluble sulfides Al3+, Co2+, Cr+, Fe²+, Fe3+, Ni2+, Mn2+, Zn2+ form base-insoluble sulfides or hydroxides Ba?+, Ca?+, Mg²+, S²+ form insoluble carbonates Lit, Nat, K+, NH completely soluble
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