A solution contains 2.0 x 10-4 M Ag+ and 1.5x10-3 M Pb2+ . If KI is added, will AgI (Ksp = 8.3 x 10-17) or PbI2 (Ksp = 7.9 x 10-9 ) precipitate? What are the specific concentrations of I - needed? ANS: AgI will precipitate out first.           [I- ] for AgI = 4.2 x 10-13 M           [I- ] for PbI2= 2.3 x 10-3 M

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Chapter11: Solving Equilibrium Problems For Complex Systems
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Problem 11.16QAP
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A solution contains 2.0 x 10-4 M Ag+ and 1.5x10-3 M Pb2+ . If KI is added, will AgI (Ksp = 8.3 x 10-17) or PbI2 (Ksp = 7.9 x 10-9 ) precipitate? What are the specific concentrations of I - needed?

ANS: AgI will precipitate out first. 

         [I- ] for AgI = 4.2 x 10-13 M 

         [I- ] for PbI2= 2.3 x 10-3 M 

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