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- A solution of FESCN2+ has a concentration of 1.00 x 10-M and an absorbance of 0.755. What is the concentration of an FeSCN2+ solution with an absodbance of 0.491? Enter your answer in scientific notation, with one decimal place, as follows: 2.3e-4 or 2.3E-4 Do not include units and note that 10 and x are NOT USED in this type of scientific notation. Question 3 of 26>»In the Analytical Chemistry laboratory, one of the B.Sc student Ms. Fatma wanted to analyze the presence of Iron(II) ion in the water samples collected from Sohar Industrial Area in the Sultanate of Oman and analyzed by Spectrophotometric method. (1) 250.00 mL of this water sample (Solution A) known to contain unknown amount of FeSO4. She has diluted Solution A by a dilution factor 10 to make 250.00 mL solution, which she labeled Solution B. Using Spectrophotometer, she has measured the absorbance value (0.642) for Solution B at 508 nm using 1.00 cm cell (cuvet). The molar absorptivity value for Fe2* ion at 508 nm is ɛ508 = 30.8 M-1cm1. (i) What volume of the solution A did she require to make the 250.00 mL of Solution В? (ii) in (i)? What instrument should she use to transfer the volume of the Solution A calculated (ii) Concentration of FeSO4 in Solution B. (iv) Concentration of FeSO4 in Solution A. Mass of FeSO4 in Solution A (Show your calculation) (v)A student creates a calibration plot for serial dilutions of Cu(NO3)2. A graph of concentration in M (x-axis) versus absorbance (y-axis) gives a linear trendline of y = 0.345x - 0.11. e.) Copper(II) nitrate has a solubility of 83.5 g in 100 g of water. Calculate the percent error in the student's concentration.
- You are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.You want to make a solution of the primary standard sodium oxalate. It has a molecular mass of 133.999 g/mol (no error). Your analytical balance has an error of 0.2 mg. You add some weighing paper to the balance and it reads a mass of 0.23626 g. You then add sodium oxalate onto the weighing paper until the mass registers as 2.8539 g. You carefully transfer this to a 250.0 ml volumetric flask with an error of 0.1 ml and dissolve the sodium oxalate in a sufficient volume of water. What is the concentration of the oxalic acid (in M) and what is the absolute error (also in M).Consider the following statement: Statement I: Matrix is equal to blank plus the analyte. Statement II: In 250-mL water sample, 50-mL is subjected for analysis. The 250-mL is the aliquot. Statement IlI: When the technical grade chemical is used to prepare solution, a primary standard is used to standardized and determine the actual concentration of solution. Which of the following option is correct? OA Statement I is correct and statement || and II are incorrect OB Statement I and II are correct and statement II is incorrect OC Statement I and III are correct and statement II is incorrect O D.Statement II and III are correct and statement I is incorrecct OE Statement I, fl, and ll are correct
- (Concentration) You are tasked to prepare 50.000 ppm of a caffeine standard for an analysis. If you need to prepare 500.00 (±0.08) mL of this solution, how much (in grams) solid, pure caffeine are you supposed to dissolve? What absolute uncertainty is associated with your mass measurement if the prepared solution has a 0.12% percent relative uncertainty? Write your answer using the appropriate number of digits. Note that the formula mass of caffeine is 194.194 g/mol with negligible error. (absolute error) How many significant figures does your reported mass have? --- (number of sig. figs.)A solution of FESCN2+ has a concentration of 1.00 x 10-2M and an absorbance of 0.755. What is the concentration of an FESCN2+ solution with an absorbance of 0.373? Enter your answer in scientific notation, with one decimal place, as follows: 2.3e-4 or 2.3E-4 Do not include units and note that 10 and x are NOT USED in this type of scientific notation.Exactly 10.00-mL aliquots of a solution containing phenobarbital were measured into 50.00-mL volumetric flasks and made basic with KOH. The following volumes of a standard solution of phenobarbital containing 2.000μg/mL of phenobarbital were then introduced into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50, 2.00 mL. The fluorescence of each of these solutions was measured with a fluorimeter, which gave values of 3.26, 4.80, 6.41, 8.02, 9.56, respectively. a. plot the data. b. derive a least squares equation for the data plotted in (a). c. find the concentration of phenobarbital from the equation in (b). d. calculate a standard deviation for the concentration obtained in (c).
- Based on this student data, calculate the average molarity of the NaOH solution. Standard: KHP = potassium hydrogen phthalate, MM 204.4 g/mol Student Data Trial 1 E KHP mL initial: NaOH mL final: NaOH 2.02 0.57 19.25 Trial 2 2.05 19.25 39.80 Trial 3 1.99 1.65 20.753.1524 g HCI (FW 36.46) was diluted with 45 mL water and titrated with 1.0149 M NAOH (FW 40) using methyl red as indicator. 28.02 mL of NAOH was required to neutralize the HCI. Calculate the percentage w/w of HC. Record your answer in decimal notation to 2 decimal places. Answer = % w/w %3D00 mL of a diprotic acid primary standard solution was accurately prepared to a concentration of 0.1431 M. Three samples of this primary standard solution were used as samples in a titration to standardize an aqueous solution of sodium hydroxide, NaOH, which would be used as a titrant. Using the following table of data for the titration of the primary standard acid with NaOH, calculate the average concentration of NaOH. Trial # Volume of primary standard Initial titrant volume Final titrant volume 1 10.00 mL 8.21 mL 27.22 mL 2 10.00 mL 27.22 mL 46.23 mL 3 10.00 mL 30.28 mL 49.29 mL 0.1506 M 0.0753 M 0.0376 M 0.1431 M 0.0526 M