A student wanted to measure the concentration of cobalt(II) ion in an aqueous solution. For the cathode half-reaction, she used a silver electrode with a 0.51 M solution of AgNO3. For the anode half-reaction, she used a cobalt electrode dipped into the aqueous solution. If the cell gave a potential of 1.043 V at 25 °C, what was the concentration of Co2+ in the solution? Half-reaction E° (V) Ag*(aq) + e - Ag(s) +0.7996 Co2+(aq) + 2 e - -0.28 Co(s) Your Answer: Answer units

A student wanted to measure the concentration of cobalt(II) ion in an aqueous solution. For the cathode half-reaction, she used a silver electrode with a 0.51 M solution of AgNO3. For the anode half-reaction, she used a cobalt electrode dipped into the aqueous solution. If the cell gave a potential of 1.043 V at 25 °C, what was the concentration of Co2+ in the solution? Half-reaction E° (V) Ag*(aq) + e - Ag(s) +0.7996 Co2+(aq) + 2 e - -0.28 Co(s) Your Answer: Answer units

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter18: Electrochemistry

Section: Chapter Questions

Problem 18.50QE

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An electrolysis experiment is performed to determine the value of the Faraday constant (number of coulombs per mole of electrons). In this experiment, 28.8 g of gold is plated out from a AuCN solution by running an electrolytic cell for two hours with a current of 2.00 A. What is the experimental value obtained for the Faraday Constant?
Halide ions can he deposited at a silver anode, the reaction being Ag(s) + X- AgX(s) +e- Suppose that a cell was formed by immersing a silver anode in an analyte solution that was 0.0250 M Cl-,Br-, and I -ions and connecting the half-cell to a saturated calomel cathode via a salt bridge. (a) Which halide would form first and at what potential? Is the cell galvanic or electrolytic? (b) Could I- and Br- be separated quantitatively? (Take 1.00 l0-5 M as the criterion for quantitative removal of an ion.) If a separation is feasible, what range of cell potential could he used? (c) Repeat part (b) for I- and Cl-. (d) Repeat part (b) for Br- and Cl-.
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How long would it take to electroplate a metal surface with 0.500 g nickel metal from a solution of Ni2+ with a current of 4.00 A?
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An aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?