Incident beam angle to the grating: 55 degrees A student will be performing analysis of water samples collected from the Lake Eymir to determine Feconcentration using a flame atomic absorption spectrometer (FAAS) equipped with Echellette-type ofgrating and Fe-Ge-Pt multielement Hollow Cathode Lamp (HCL) for which high-resolution emissionspectrum is provided in the above spectrum. The monochromator of the instrument has a focal length of100 cm and a collimating mirror with a diameter of 3.5 cm. The grove density of the monochromator is2000 blaze/mm and 10.0 mm of the grating surface is illuminated. Consider the figures and the informationgiven above and answer the following questions:a) In this analysis, the student will be using the Fe emission peak of HCL, which appears at 193.7268 nm.At what reflection angle(s) the first order and second order spectra of Fe with 193.7268 nm wavelengthwill be observed?b) What would be the first-order and the second-order reciprocal linear dispersion of the spectrometerfor the given parameters?c) What would be the first-order and second order resolving power of the monochromator?d) Discuss the advantages and disadvantages of first and second-order spectra and then decide which oneshould be used for the analysis.e) If the slit width is 0.1 mm, can the monochromator resolve the 193.7268 nm Fe emission line from Ptemission line (193.7424 nm)? If not, what slit width setting would be required to resolve these two lines?Consider only first-order reciprocal dispersion. Show your calculations and explain briefly.f) What is the light gathering power of the instrument? Compare the performance of the instrument interms of S/N ratio with another instrument that has light gathering power, F, of f/4.

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A student will be performing analysis of water samples collected from the Lake Eymir to determine Fe concentration using a flame atomic absorption spectrometer (FAAS) equipped with Echellette-type of grating and Fe-Ge-Pt multielement Hollow Cathode Lamp (HCL) for which high-resolution emission spectrum is provided in the above spectrum. The monochromator of the instrument has a focal length of 100 cm and a collimating mirror with a diameter of 3.5 cm. The grove density of the monochromator is 2000 blaze/mm and 10.0 mm of the grating surface is illuminated. Consider the figures and the information given above and answer the following questions:

A student will be performing analysis of water samples collected from the Lake Eymir to determine Fe concentration using a flame atomic absorption spectrometer (FAAS) equipped with Echellette-type of grating and Fe-Ge-Pt multielement Hollow Cathode Lamp (HCL) for which high-resolution emission spectrum is provided in the above spectrum. The monochromator of the instrument has a focal length of 100 cm and a collimating mirror with a diameter of 3.5 cm. The grove density of the monochromator is 2000 blaze/mm and 10.0 mm of the grating surface is illuminated. Consider the figures and the information given above and answer the following questions:

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter4: Least-squares And Calibration Methods

Section: Chapter Questions

Problem 8P

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A sample of body serum is to be analysed for sodium by flame emission spectroscopy. 1.00cm' aliquot of serum was pipetted into each of two 50.0cm' volumetric flasks. The first flask was diluted to volume with deionised water. The absorbance of this first solution was0.350. To the second flask 10.0 cm' of a 25.0 ppm sodium standard was added and the flask made up to volume with deionised water. The absorbance of this second solution was 0.720.(i) Calculate the concentration of the sodium in the body serum in mg dm-3.
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