4 3. A transition metal chloride (MCI2) combines with pyridine and DMSO to give a metalcomplex with a formula MCI2(DMSO)(py). The FT-IR spectrum (in the range from 1425to 300 cm-') of the complex is shown below.toCIL = DMSOMCI, + py + 3Lpy = N140012001000800600400wavenumber / cm(a) Based on the spectral information above, through which atom do the DMSO ligandbond to central M' ion?(b) Explain your answer in (a) above..

To which atom does the DMSO ligand bond to central M2+ ion.

A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N

A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.30QAP

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