(a) Using Valence bond theory explain the geometry and magnetic behaviour by [Cr(NH3)6]3+ . (At. no. Cr = 24)(b) Write the IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl.

Q: 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you…

A: Step : 1             The required answer is follows as :

Q: K3[Al(C2O4)3]*3H2O is colorless?

A: The given compounds are coordination compounds. Coordination compounds are those compounds which on…

Q: . Explain why compounds of Sc3+ are colorless, but compounds ofTi3+ are colored?

A: Color of d-block compounds are generally coloured due to d-d transitions

Q: Draw the SALC set for the ferrocene ligand set, describing in detail the steps used. Which isomer…

A: In case of ferrocene, the two possible conformations are eclipsed and staggered with a point group…

Q: Why can NH3 serve as a ligand but BH3 cannot?

A:

Q: Ligand A, B, and C form complexes with a metal cation resulting to  violet, indigo, and blue aqueous…

A:

Q: Draw the structures and give the stock names of complexes that can satisfy the following condition:…

A: Chiral compound is a molecule that has asymmetric center that is no plane or center of symmetry.…

Q: A transition metal, M, is coordinated in an octahedral fashion to the following ligands Two chloro…

A: We get a total of 6 Isomers.2 isomers where Cl atoms are trans.Since a sigma plane passes through…

Q: Explain the following observations : Zn2+ salts are colourless.

A: The reason for Zn2+ salts are colourless has to be given.

Q: All the following statements are correct EXCEPT:  a. The pattern of d orbital splitting is…

A: In coordination chemistry, central metal ion is bonded to ligand. Ligand donate electrons to central…

Q: the complex [CrO7]² is bright orange colored, suggest reason for that ?

A: In this question, we will discuss about why complex [Cr2O7]2- ion is bright orange color.  You can…

Q: Predict whether these complexes would be labile or inert and explain your choices. The magnetic…

A: Dear Subscriber!  You have posted multiple questions. As per our policy, we have solved first one…

Q: Question attached

A: All coordination complexes show 18 electron rule.

Q: Which of the following is most likely to bond to Ni2+ as a ligand?  Explain.   CH3-CH2-CH3…

A: The answer is given as follows

Q: Compounds with lone pair of electrons are able to form complexes via the donation of electrons into…

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Q: "Are all the organometallic complexes stable to moisture and temperature?" Explain.

A: the thermal stability organometallic compound generally decreases from the lightest to the heaviest…

Q: Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers. (ii). Calculate…

A: Isomers are those compounds which have same chemical formula but they are different from each other.…

Q: Describe clearly how crystal field theory explains satisfactorily the magnetic moment of transition…

A:

Q: Draw the geometry of: diquadiododdinitropalladium(IV) - and all its ligands trans

A: The complex given is diquadiododdinitropalladium(IV).

Q: a. Classify the isomer below and give the name of the isomers. [Cr(CO)6][CoCl6] and [Co(CO6)][CrCl6]…

A: The detailed solution of your question given below-- Since, we know that the concept of isomers in…

Q: Define the ambidentate ligand and give two examples.

A: Those ligand which can donate electrons from two different atom site but donate from 1 site at one…

Q: "Ligand field theory provides a basis for explaining the chemical behaviour of octahedral transition…

A: LFT is known as 'Ligand Field Theory' that is the modified crystal field theory. In crystal field…

Q: Why d7,d8,d9 complexes prefer square planar with pi acceptor strong field ligands

A: Ligands are those species which forms a bond with metal by donating the electrons. Pi acceptor…

Q: Suppose that rather than reacting copper(II) with ammonia, you had reacted it with an ammonium salt,…

A: • It is given that rather than reacting copper(ll) with ammonia, one had reacted copper(Il) with an…

Q: 1. Draw the partial MO diagram for a [Fe(OH;)6J** using concepts from Ligand Field Theory. Fill in…

A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…

Q: Draw the structures and give the stock names of complexes that can satisfy the following conditions:…

A:

Q: a) Trialkylphosphine and ammonia are both strong-field ligands. However, experimental data show that…

A: Solution for a, PR3 ligands cause higher Δo than the NH3 because PR3 is σ-donor as well as…

Q: Inorganic Chemistry (i) Define spectrochemical series (ii) Explain the difference between…

A: Given  Name of series = spectrochemical series  Definition = ? Weak field ligand  = ? strong field…

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Q: CO is considered a strong field ligand and I- is considered a weak field ligand. Give an axplanation…

A: In an octahedral complex, central transition metal atom is attached by six ligands.  The energy…

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: Mo(PMes)3(C6HS)2

A:

Q: If A, B, C, and D are four - electrically neutral - different single-tooth substituents, what kind…

A: To show the kind of isomerism shown by the tetrahedral complex [ZnABCD]2+, where A, B, C and D are…

Q: Which of the following is NOT a monodentate ligand?     Carbon monoxide     Water     Oxalate…

A:

Q: Draw a Lewis structure for the cyclopentadienyl ligand (C5H5)- and explain why it is more likely to…

A: Cyclopentadienyl anion ligand, (C5H5)-, it is formed by the deprotonation of cyclopentadiene,…

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: From given  Enantiomers are optical isomers which are mirror images to each other so we are finding…

Q: EDTA ligand consider as

A: The word ligand means 'to bind'. Ligand is defined as a molecule that gives an electron pair to the…

Q: 9. Describe the various ligand classes and give an example in each case! 10. Justify why…

A: Ligand is atom or ion which donate electron density to metal ion.

Q: Can the ammonia ligand engage in linkage isomerism?

A: Linkage isomerism is shown by ligands that are similar in their compositions but differ in the atoms…

Q: A complex of nickel ions, Ni2*, with 1,2-diaminoethane is octahedral in shape with a co-ordination…

A: Ni2+ forms an octahedral complex with1,2-diaminoethane (NH2C2H4 -NH2) with coordination 6. Since,…

Q: Using your knowledge of Ligand Field Theory, Although oxygen is more electronegative than nitrogen,…

A:

Q: (a) [Cr(H2O)6]°+ is violet, but [Cr(NH3)6]* is yellow. Explain this observation using LFT. (b)…

A: Note:- Both questions are from different topics so I will be solved first question for you or resend…

Q: Give the molecular orbital diagram for the diatomic fluorine 2- ion, including labels for all…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: f)) "Crystal field theory provides a basis for explaining the features of transition metal…

A: Two statements based on coordination complexes, which are to be explained.

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into :  1.) Only sigma donor 2.)…

Q: iv. Compound 2 has a distorted octahedral geometry, with four short and two longer Co-P bond…

A: The Phosphine ligand is a strong field ligand than "en" ligand because in phosphine ligand contains…

Q: (a) Explain the major difference between the number of oxi-dation states of most transition elements…

A: a.

Q: b) Calculate the orbital multiplicity for a Cr3+ assuming it is a free ion (Not complex). c)…

A: Orbital multiplicity of a metal is its total no.of orientations of orbital angular momentum L. which…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.