A water sample (pH=7.8) contains 94mg/L of calcium, 28mg/L of magnesium, 14mg/L of sodium and 31mg/L of potassium. What is the total hardness (TH) in (a) meq/L and (b) mg/L as CaCO3. Besides, what is the alkalinity of sample if presence of 135mg/L HCO₂ and 134mg/L of SO (Given: MW of Ca=40, K-39.1, S-32, Mg-24.3, Na-23, 0-16, C=12, H=1)
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- On the redox titration experiment, Standardization of Na2S2O3 with KIO3 standard solution, what can be replaced KIO3 to make safer solvent and auxiliaries( reduced toxic waste)? explain why?Calcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)1. Find the number of millimoles of solute in a. 226 ?? of 0.320 ? HClO4. b. 25.0 ? of 8.05 ? 10−3 ? K2CrO4. c. 6.00 ? of an aqueous solution that contains 6.75 ??? of AgNO3. d. 537 ?? of 0.0200 ? KOH. 2. Describe the preparation of a. 5.00 ? of 0.0500 ? KMnO4 from the solid reagent. b. 4.00 ? of 0.250 ? HClO4, starting with an 8.00 ? solution of the reagent. c. 400 ?? of a solution that is 0.0250 ? in I2, starting with MgI2. d. 200 ?? of 1.00% (?/?) aqueous CuSO4 from a 0.365 ? CuSO4 solution. e. 1.50 ? of 0.215 ? NaOH from the concentrated commercial reagent [50% NaOH (w/w), ?? ?? = 1.525]. f. 1.50 ? of a solution that is 12.0 ??? in K+, starting with solid K4Fe(CN)6. 3. Exactly 75.00 ?? of a 0.3132 ? solution of Na2SO3 were treated with 150.0 ?? of 0.4025 ? HClO4 and boiled to remove the SO2 formed. a. What was the mass in grams of SO2 that was evolved? b. What was the concentration of the unreacted reagent (Na2SO3 or HClO4) after thereaction was complete?
- The distribution coefficient, k = concentration in hexanes concentration in water, between hexanes and water for solute A is 6.0. What weight of A would be removed by hexanes from a solution of 10 grams of A in 100 mL of water by a single extraction with 100 mL of hexanes? what weight of A would be removed by two successive extractions with 50 mL of hexanes? How many mL of hexanes would be required to remove 98% of A from a solution of 10 grams of A in 100 mL of water?What volume (V) of 0.100M (moles) KMnO4 would be required to Titrate 0.23g of K2{Cu(Cu2O4)2} * H20?Firstly, What is the final molar concentration of a 500.0ml solution prepared from 15.0 ml of a 12.0 M solution of sulfuric acid? Secondly, solid potassium permanganate and standard laboratory equipment are available. Briefly describe how you prepare 100.0 ml solution of 0.050 M potassium permanganate? Potassium permanganate Mr= 158.03 g mol-1 Thirdly, are methonal (CH3OH) and acetic acid (CH3COOH) expected to be miscible? explain with reasoning
- The distribution coefficient, k = concentration in hexanes concentration in water, between hexanes and water for solute A is 6.0. What weight of A would be removed by hexanes from a solution of 10 grams of A in 100 mL of water by a single extraction with 100 mL of hexanes? a.) What weight of A would be removed by two successive extractions with 50 mL of hexanes? b.)How many mL of hexanes would be required to remove 98% of A from a solution of 10 grams of A in 100 mL of water?If a water has a carbonate alkalinity of 120.00 mg/L as the ion and a pH of 10.30, what is the bicarbonate alkalinity in mg/L as the ionThe concentration of Cl- in ocean water is about 500-600 mM. The baywater is diluted by a factor of 12.5 using a 20.00 mL volumetric pipet and a 250 mL volumetric flask. Using a 15.00 mL volumetric pipet, 15.00 mL are transfered into each of three clean erlenmeyer flasks. 10 mL of 1% dextrin solution, 20 mL of de-ionized water, and 3-4 drops of indicator are added and titrate each with the AgNO3 solution. What is the dilution factor? What is the volume of the diluted bay water? What is the volume of bay water?
- What is the solubility of Ag2CO3 in mol/L?Give an answer with 4 significant figures.If 50.0 mL of Thiosulfate solution are required to titrate the 12 liberated from an excess of Kl by 0.3000 grams of potassium lodate, calculate (a) normality of the thiosulfate solution (b) value of each milliliter of Thiosulfate solution in terms of grams of 12.If 50.0 mL of Thiosulfate solution are required to titrate the I2 liberated from an excess ofKI by 0.3000 grams of potassium Iodate, calculate (a) normality of the thiosulfate solution(b) value of each milliliter of Thiosulfate solution in terms of grams of I2.