A vehicle airbag system works by using a series of chemical reactions. When sensors in the system detect a collision, a heat source instantly causes the decomposition of sodium azide at 300oC. This first reaction produces sodium metal and nitrogen gas. The formation of the nitrogen gas inflates the airbag, but unfortunately, the other product, sodium metal, is extremely dangerous and highly reactive. The sodium metal must undergo an immediate secondary reaction to transform into a safer substance. That’s where potassium nitrate gets involved. In the secondary reaction, sodium metal reacts with the potassium nitrate to form potassium oxide, sodium oxide, and additional nitrogen gas. This secondary generation of nitrogen gas also fills the airbag. Excess gas from the secondary reaction gets vented from e airbag. Finally, in the third and fourth reactions, the sodium oxide and potassium oxide react with silicon dioxide separately to product harmless and stable silicate glasses sodium silicate (Na2SiO3) and potassium silicate (K2SiO3) respectively. The average volume for a driver’s side airbag is 56 L and for the passenger’s side it is 120 L. The pressure needed for the airbags to inflate properly is 1.87 atm. a. Write balanced equations for the four reactions that occur during airbag deployment. b. What is the minimum amount of sodium azide in grams necessary for the airbags to deploy properly? c. How much potassium nitrate and silicon dioxide are necessary to convert products of the reaction harmless and stable solids?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
Section: Chapter Questions
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A vehicle airbag system works by using a series of chemical reactions. When sensors in the system detect a collision, a heat source instantly causes the decomposition of sodium azide at 300oC. This first reaction produces sodium metal and nitrogen gas. The formation of the nitrogen gas inflates the airbag, but unfortunately, the other product, sodium metal, is extremely dangerous and highly reactive. The sodium metal must undergo an immediate secondary reaction to transform into a safer substance. That’s where potassium nitrate gets involved. In the secondary reaction, sodium metal reacts with the potassium nitrate to form potassium oxide, sodium oxide, and additional nitrogen gas. This secondary generation of nitrogen gas also fills the airbag. Excess gas from the secondary reaction gets vented from e airbag. Finally, in the third and fourth reactions, the sodium oxide and potassium oxide react with silicon dioxide separately to product harmless and stable silicate glasses sodium silicate (Na2SiO3) and potassium silicate (K2SiO3) respectively. The average volume for a driver’s side airbag is 56 L and for the passenger’s side it is 120 L. The pressure needed for the airbags to inflate properly is 1.87 atm.

a. Write balanced equations for the four reactions that occur during airbag deployment.

b. What is the minimum amount of sodium azide in grams necessary for the airbags to deploy properly?

c. How much potassium nitrate and silicon dioxide are necessary to convert products of the reaction harmless and stable solids?

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