A)A molecule which possesses an inversion center is said to be centrosymmetric. We have seen that IR and Raman spectroscopy can be used to distinguish between alternative structures of molecules. If one is considering two possible structures of a molecule, one of which is centrosymmetric and one of which is not (for example, a molecule with formula ML4 could be square-planar or tetrahedral), the following rule is useful. In a centrosymmetric molecule, a given vibrational mode cannot be active in BOTH the IR and Raman spectrum, while in a non-centrosymmetric molecule, there is no such exclusion. Look at the character tables for a number of point groups and justify this rule.
A)A molecule which possesses an inversion center is said to be centrosymmetric. We have seen that IR and Raman spectroscopy can be used to distinguish between alternative structures of molecules. If one is considering two possible structures of a molecule, one of which is centrosymmetric and one of which is not (for example, a molecule with formula ML4 could be square-planar or tetrahedral), the following rule is useful. In a centrosymmetric molecule, a given vibrational mode cannot be active in BOTH the IR and Raman spectrum, while in a non-centrosymmetric molecule, there is no such exclusion. Look at the character tables for a number of point groups and justify this rule.
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
Section: Chapter Questions
Problem 1E
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