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- Determine the point groups of the following molecules. a Hydrogen selenide, H2Se b Partially deuterated hydrogen sulfide, or HDS c The chair conformer of cyclohexane, C6H12 d The boat conformer of cyclohexane, C6H12Determine the point groups of the following molecules. a Hydrogen peroxide, H2O2 it is not planar. b Allene, CH2=C=CH2 c D-alanine Its absolute stereochemistry can be found in any good organic or biochemistry textbook. d L-alanine, and compare with part c above.a Unlike methane, bromochlorofluoromethane (CHBrClF) is chiral. Determine all symmetry elements that are present in CHBrClF and identify its point group. b If the fluorine in this molecule were substituted with a hydrogen atom, what is the point group for the new molecule? Is it chiral?
- Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.Identify the symmetry species of the Symmetry Adapted Linear Combination (SALC) ? = ?? ′ − ?? ′′ in the C2v molecule NO2, where ?? ′ is a 2px orbital on one O atom and ?? ′′ is a 2px orbital on the other O atom. please show your reasonings from the basics thank youConsider the 3?? 2 orbital of the central atom of a molecule with symmetry C2v. To which symmetry representation does 3?? 2 belong to? Justify graphically your answer. the answer is attched but can you please give the reasonings because im not understanding it
- How to determine symmetry elements, σh and σν and how to differentiate between both. Also , how is σh related to E.Identify the symmetry species of the Symmetry Adapted Linear Combination (SALC) ? = ?′ − ?′′ in the C2v molecule NO2, where ?′ is a 2px orbital on one O atom and ?′′ is a ???? 2px orbital on the other O atom.Consider the 3?? 2 orbital of the central atom of a molecule with symmetry C2v. To which symmetry representation does 3?? 2 belong to? Justify graphically your answer. This is the diagram answer but can you please explain the answer with the very basics thank you
- For the molecules below determine all the symmetry elements and the symmetry point group. a) H2O. b) NH3. c) CCl4. d) CH2Cl2. e) Furan. f) XeF4. g) SF6 h) cis-dichloroethene. i) trans-dichloroethene. j) eclipsed ferrocene. k) staggered ferrocene. l) CHClBrF.9- Write all symmetry elements and point group of PCI5 molecule. (Draw the shape)Consider the three following molecules and answer the questions below.HC≡CHH2C=CH2H3C-CH3 (3 conformers with different symmetry)(a) For each molecule, including all conformers as indicated, draw the molecule, assign it toits point group, and draw on the diagram the symmetry elements that were used to makethe assignment. State in each case whether or not the species is dipolar and/or chiral.(b) If one hydrogen atom in each molecule is substituted by a chlorine atom, sketch the newmolecules and assign them to their point group. For this set of mono-chloro compounds: state the most common point group state how many are chiral state how many are dipolar state which molecule/conformer has the highest symmetry point group state which molecule/conformer has the lowest symmetry point group identify which of these molecules/conformers have three different H atomenvironments(c) For the dichlorinated versions of the molecules/conformers considered in part (a): state the most common point…