always get a value less than the theoretical value

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter29: Supercritical Fluid Chromatography And Extraction
Section: Chapter Questions
Problem 29.1QAP
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Why we always get a value less than the theoretical value for van’t Hoffs law ?

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