An ideal gas expands in a process in which its pressure depends on the volume as p= p,ea, where Po and a are two positive constants. If n is the number of moles in the gas, the maximum tempera- ture that it will attain in this process is (R is the universal gas costant) -av

An ideal gas expands in a process in which its pressure depends on the volume as p= p,ea, where Po and a are two positive constants. If n is the number of moles in the gas, the maximum tempera- ture that it will attain in this process is (R is the universal gas costant) -av

Principles of Physics: A Calculus-Based Text

5th Edition

ISBN:9781133104261

Author:Raymond A. Serway, John W. Jewett

Publisher:Raymond A. Serway, John W. Jewett

Chapter16: Temperature And The Kinetic Theory Of Gases

Section: Chapter Questions

Problem 8OQ

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One cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.
Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.
For a temperature increase of 10 at constant volume, what is the heat absorbed by (a) 3.0 mol of a dilute monatomic gas; (b) 0.50 mol of a dilute diatomic gas; and (c) 15 mol of a dilute polyatomic gas?
Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS
A gas is at 200 K. If we wish to double the rms speed of the molecules of the gas, to what value must we raise its temperature? (a) 283 K (b) 400 K (c) 566 K (d) 800 K (e) 1 130 K
Two containers hold an ideal gas at the same temperature and pressure. Both containers hold the same type of gas, but container B has twice the volume of container A. (i) What is the average translational kinetic energy per molecule in container B? (a) twice that of container A (b) the same as that of container A (c) half that of container A (d) impossible to determine (ii) From the same choices, describe the internal energy of the gas in container B.
An ideal gas is enclosed in a cylinder with a movable piston on top of it. The piston has a mass of 8 000 g and an area of 5.00 cm2 and is free to slide up and down, keeping the pressure of the gas constant. How much work is done on the gas as the temperature of 0.200 mol of the gas is raised from 20.0C to 300C?
An ideal gas initially at 300 K undergoes an isobaric expansion at 2.50 kPa. If the volume increases from 1.00 m3 to 3.00 m3 and 12.5 kJ is transferred to the gas by heat, what are (a) the change in its internal energy and (b) its final temperature?
An ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?
When a gas undergoes an adiabatic expansion, which of the following statements is true? (a) The temperature of the gas does not change. (b) No work is done by the gas. (c) No energy is transferred to the gas by heat. (d) The internal energy of the gas does not change. (e) The pressure increases.
A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P17.68). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state. (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally. (f) Find Q, W, and Eint for each of the processes. (g) For the whole cycle A B C A, find Q, W, and Eint. Figure P17.68
On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?