In the gas phase the production of phosgene from chlorine and carbon monoxide proceeds by the following mechanism :

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.84P
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In the gas phase the production of phosgene from chlorine and
carbon monoxide proceeds by the following mechanism :
Cl₂ = 2 CI
constants)
FAST Equilibrium (use k1 and k-1 for rate
COCI FAST Equilibrium (use k2 and k-2 for rate
Cl + CO
constants)
COCI+ Cl₂ ⇒ COCl₂ + CI SLOW (use k3 for rate constant)
Overall: CO + Cl₂ ⇒ COCI₂
a. Write the rate law for this reaction
b. Which species are intermediates ?
On the back
Transcribed Image Text:In the gas phase the production of phosgene from chlorine and carbon monoxide proceeds by the following mechanism : Cl₂ = 2 CI constants) FAST Equilibrium (use k1 and k-1 for rate COCI FAST Equilibrium (use k2 and k-2 for rate Cl + CO constants) COCI+ Cl₂ ⇒ COCl₂ + CI SLOW (use k3 for rate constant) Overall: CO + Cl₂ ⇒ COCI₂ a. Write the rate law for this reaction b. Which species are intermediates ? On the back
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Are those R or K  in step 1-2 after the = sign?

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