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- Determine the following from the Txy diagram of a two-component (A and B) solid-liquid system: Composition of the eutectic mixture Consider a mixture with overall B composition of 0.57. What is the ratio of the amount of solid containing 0.67 B and 0.33 A to the amount of the eutectic mixture at the eutectic temperature? What is the chemical formula of the solid represented by the vertical phase boundary passing through point g? (Hint: use mole fractions of A and B to answer this)A liquid-vapour mixture whose composition is 60 mole % of benzene is contained within a vessel at 60C. What fraction of moles are both methanol and in the liquid phase?Phenol and water form non-ideal liquid mixtures. When 7.32 g of phenol and 7.95 g of water are mixed together at 60 °C they form two immiscible liquid phases with mole fractions of phenol of 0.042 and 0.161. (i) Calculate the overall mole fraction of phenol in the mixture. (ii) Use the lever rule to determine the relative amounts of the two phases.
- Phenol and water form non-ideal liquid mixtures. When 7.32 g of phenol and 7.95 g of water are mixed together at 60 °C they form two immiscible liquid phases with mole fractions of phenol of 0. 0 42 and 0 .161 . (a) Calculate the overall mole fraction of phenol in the mixture. (b) Use the lever rule to determine the relative amounts of the two phases .In the system NaCl-H2O, a simple eutectic is observed at −21.1°C for a solution containing 23.3% by weight NaCl where NaCl•2H2O and ice crystallize out of the mixture. At a composition of 27% by weight of NaCl and at −9°C a peritectic point exists where the dihydrate decomposes to form anhydrous NaCl. The temperature coefficient of solubility of anhydrous NaCl is very small and positive. Make a rough sketch for the system showing clearly the phases in equilibrium in the various areas and along the curves of the diagram.Sketch the non-ideal vapour pressure-composition curve of element X and nitrous acid, HNO2 where the composition of azeotropic mixture is 40% X at 40ºC and the boiling point of X is higher than HNO2. Explain the vapour pressure of each composition and distillation process of above mixture using the curve
- There are two separate phases, one with a composition of 12% phenol and the other with a composition of 60% phenol, from a 210 gram phenol-water mixture with 35% phenol at 60oC. Calculate the masses of these phases.non idealities in liquid mixtures 1) which non-ovalent force is responsible for most of the non-idealities in liquid mixtures? 2) if a binary liquid mixture exhibits a positive deviation from rault's law, what are the possible values of the acivity coefficients of the two components? 3)are the following mixtures expected to be non ideal or ideal? i) cyclohexane and cycloctane ii) isopropanol and water iii)chloroform and acetone iiii) benzene and tolueneIron(II) chloride (melting point 677 °C) and potassium chloride (melting point 776 °C) form the compounds KFeCl3 and K2FeCl4 at elevated temperatures. KFeCl3 melts congruently at 399 °C and K2FeCl4 melts incongruently at 380 °C. Eutectics are formed with compositions x = 0.38 (melting point 351 °C) and x = 0.54 (melting point 393 °C), where x is the mole fraction of FeCl2. The KCl solubility curve intersects the A curve at x = 0.34. Sketch the phase diagram. State the phases that are in equilibrium when a mixture of composition x = 0.36 is cooled from 400 °C to 300 °C.
- Determine the following from the Txy diagram of a two-component (A and B) solid-liquid system: a) Consider a mixture with overall B composition of 0.57. What is the ratio of the amount of solid containing 0.67 B and 0.33 A to the amount of the eutectic mixture at the eutectic temperature? b) What is the chemical formula of the solid represented by the vertical phase boundary passing through point g? (Hint: use mole fractions of A and B to answer this) c) Suppose we have a solid mixture represented by point k. How much of the solid in Problem 4c is in equilibrium per kg of pure B?Using the Mg-Pb phase diagram below, if you start at point A andcool down very slowly to room temperature (point D), sketch the microstructure associated with each letter, determine what phases are present at each letter, determine the compositions for each phase, and determine the weight in each phase. The Mg-Pb mixture has 20 wt. % Pb in it. You start with 100 kg. A. 700ºC B. 600ºC C. 400ºC D. 25ºCThere are two separate phases, one with a composition of 12% phenol and the other with a composition of 60% phenol, from a 210 gram phenol-water mixture at 60 °C with a composition of 35% phenol. Calculate the masses of these phases.