As the following data show, removing an electron from N₂ forms an ion with a weaker, longer bond than in the parent molecule, whereas the ion formed from O₂ has a stronger, shorter bond. Explain these facts using the MO diagrams... what else do you need to determine? Be sure to give an explanation below based on Molecular Orbital theory and to show your work using the correct MO diagram on the next page. N₂ N₂+ 0₂ O₂+ Bond energy (kJ/mol) 945 841 Bond length (pm) 110 112 498 121 623 112

As the following data show, removing an electron from N₂ forms an ion with a weaker, longer bond than in the parent molecule, whereas the ion formed from O₂ has a stronger, shorter bond. Explain these facts using the MO diagrams... what else do you need to determine? Be sure to give an explanation below based on Molecular Orbital theory and to show your work using the correct MO diagram on the next page. N₂ N₂+ 0₂ O₂+ Bond energy (kJ/mol) 945 841 Bond length (pm) 110 112 498 121 623 112

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter17: Conjugation And Molecular Orbital (mo) Theory

Section: Chapter Questions

Problem 15E

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Similar questions

a-Draw a molecular orbital (MO) energy level diagram for NO. Label the atomic orbitals, MOs and identify the frontier orbitals. b-Explain the differences in bond dissociation energies and bond lengths on addition and removalof an electron from NO.
For each molecule or molecular ion below, calculate the bond order: N2, N2-, O2 and O2+. In this calculation, show which specifically bonding and anti-bonding molecular orbitals were used in the calculation. Please label molecular orbitals with appropriate “g” (“gerade”) and “u” (“ungerade”) subscripts.
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Construct, fully label, and populate a MO diagram for the nitrosonium anion, NO+. Based on the diagram, state which of NO+ or NO you expect to have a stronger bond.
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