At 20°C the solubility product of strontium sulphate is 4.0 x 107 mol? dm6. Compare the solubility of strontium sulphate in a) pure water and b) 0.1M NazSO4.

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Chapter17: Solubility And Complex-ion Equilibria
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Problem 17.42QP: The solubility of silver sulfate, Ag2SO4, in water has been determined to be 8.0 g/L. What is the...
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At 20°C the solubility product of strontium sulphate is 4.0 x 107 mol? dm6. Compare the solubility of strontium sulphate in a) pure water and b) 0.1M NazSO4.

Expert Solution
Step 1

The formula for strontium sulphate is SrSO4 

hence the solubility reaction of SrSO4 is

=> SrSO4 (s) -------> Sr2+ (aq) + SO42- (aq)

Hence the solubility product or equilibrium constant expression will be 

Ksp = Kc = [Sr2+ ] X [SO42- ] = 4 X 10-7 

 

Step 2

 a) Assuming the solubility of SrSO4 is s molar

Hence it means s concentration of SrSO4 will dissolve in water

Hence the concentration of ions forming will be [Sr2+ ] = s = [SO42-

Hence substituting the values we get  

s X s = 4 X 10-7          => s = solubility of SrSO4 in pure water = 6.32 X 10-4 mol/dm3 

 

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